CHEMISTRY GLOSSARY

gamma radiation    →   gama-zračenje

Gamma radiation is electromagnetic radiation of extremely short wavelength. Gamma radiation ranges in energy from about 10^-15 J to 10^-10 J (10 keV to 10 MeV) (wavelength less than about 1 pm). Gamma rays are emitted by excited atomic nuclei during the process of passing to a lower excitation state.

Gamma rays are extremely penetrating and are absorbed by dense materials like lead and uranium. Exposure to gamma radiation may be lethal.

gas washing bottle    →   boca ispiralica

Gas washing bottle or Drechsel bottle provide an inexpensive but effective method for washing or drying gases. The gas enters the bottle through the top of the central vertical tube, the lower end of which is below the surface of the washing medium. To maximize surface area contact of the gas to the liquid, a gas stream is slowly blown into the vessel through the fritted glass tip so that it breaks up the gas into many tiny bubbles. After bubbling through the medium, the gas rises to the top and exits through the side tube. It is named after the German chemist Edmund Drechsel (1843-1897).

gasoline    →   motorni benzin

Gasoline is a complex mixture of volatile hydrocarbons that may have between 5 to 12 carbons. The major components are branched-chain paraffins, cycloparaffins, and aromatics. Gasoline is most often produced by the fractional distillation of crude oil as the fraction of hydrocarbons in petroleum boiling between 30 °C and 200 °C. The quality of a fuel is measured with its octane number. Octane number is the measure of the resistance of gasoline against detonation or preignition of the fuel in the engine. The higher the octane number, the more compression the fuel can withstand before detonating. The octane number is determined by comparing the characteristics of a gasoline to isooctane with good knocking properties (octane number of 100) and heptane with bad (octane number of 0).

Geiger counter    →   Geigerov brojač

Geiger counter (Geiger-Muller counter) is a device used to detect and measure ionising radiation. It consists of a tube containing a low-pressure gas (usually argon or neon with methane) and a cylindrical hollow cathode through the centre of which runs a fine-wire anode. A potential difference of about 1 000 V is maintained between the electrodes. An ionising particle or photon passing through a window into the tube will cause an ion to be produced and the high potential will accelerate it towards its appropriate electrode, causing an avalanche of further ionisations by collision. The consequent current pulses can be counted in electronic circuits or simply amplified to work a small loudspeaker in the instrument. It was first devised in 1908 by the German physicist Hans Geiger (1882-1945). Geiger and W. Muller produced an improved design in 1928.

Pauling scale    →   Paulingova skala

Pauling scale is a numerical scale of electronegativities based on bond-energy calculations for different elements joined by covalent bonds. Electronegativity is the power of an atom when in a molecule to attract eletrons to itself. Fluorine is the most electronegative element with a Pauling electronegativity value of 4.

perfume    →   parfem

Perfumes are mixtures or alcohol solutions of natural or synthetic volatile substances of a pleasant aroma, usually containing plant ethereal oils or relative esters, ethers, aldehydes and ketones.

germanium    →   germanij

Germanium was discovered by Clemens Winkler (Germany) in 1886. The origin of the name comes from the Latin word Germania meaning Germany. It is greyish-white semi-metal. Unaffected by alkalis and most (except nitric) acids. Stable in air and water. Germanium is obtained from refining copper, zinc and lead. Widely used in semiconductors. It is a good semiconductor when combined with tiny amounts of phosphorus, arsenic, gallium and antimony.

Gibbs free energy    →   Gibbsova slobodna energija

Gibbs free energy (G) is an important function in chemical thermodynamics, defined by

where H is the enthalpy, S the entropy, and T the thermodynamic temperature. Gibbs free energy is the energy liberated or absorbed in a reversible process at constant pressure and constant temperature. Sometimes called Gibbs energy and, in older literature, simply free energy.

Changes in Gibbs free energy, ΔG, are useful in indicating the conditions under which a chemical reaction will occur. If ΔG is negative the reaction will proceed spontaneously to equilibrium. In equilibrium position ΔG = 0.

Gibbs phase rule    →   Gibbsov zakon faza

Gibbs phase rule is the relationship used to determine the number of state variables, usually chosen from among temperature, pressure, and species composition in each phase, which must be specified to fix the thermodynamic state of a system in equilibrium:

where C is the number of components in a mixture, P is the number of phases, and F is the degrees of freedom, i.e., the number of intensive variables that can be changed independently without affecting the number of phases.

global hectare    →   globalni hektar

Global hectares (gha) are hectares with world-average productivity for all productive land and water areas in a given year. Because different land types have different productivity, a global hectare of, for example, cropland, would occupy a smaller physical area than the much less biologically productive pasture land, as more pasture would be needed to provide the same biocapacity as one hectare of cropland ("ordinary" hectare is an area equal to a square that is 100 meters on each side, so a hectare has 10 000 m²). Global hectare is unit for measuring our demands on the Earth (ecological footprint) and the ability of the Earth to supply our demands (biocapacity).