CHEMISTRY GLOSSARY

mercaptans    →   merkaptani

Mercaptans are a traditional term abandoned by IUPAC, synonymous with thiols, a sulfur-containing organic compound with the general formula R-SH where R is any radical. This term is still widely used.

mineral acid    →   mineralna kiselina

Mineral acid is an acid made from minerals by chemical reaction, e.g. hydrochloric acid is produced from sodium chloride and sulphuric acid is made from sulphur.

rheology    →   reologija

Rheology is the study of the deformation and flow of materials. Has important bearing on the behaviour of viscous liquids in plastic molding.

smog    →   smog

Smog is a mixture of smoke and fog. The term is used to describe city fogs in which there is a large proportion of particulate matter (tiny pieces of carbon from exhausts) and also a high concentration of sulphur and nitrogen gases.

hydrogen    →   vodik

Hydrogen was discovered by Sir Henry Cavendish (England) in 1766. The origin of the name comes from the Greek words hydro and genes meaning water and generate. It is colourless, odourless gas, burns and forms explosive mixtures in air. Reacts violently with oxidants. Hydrogen is the most abundant element in the universe. Commercial quantities of hydrogen are produced by reacting superheated steam with methane or carbon. In lab work from reaction of metals with acid solutions or electrolysis. Most hydrogen is used in the production of ammonia and in metal refining. Also used as fuel in rockets. Its two heavier isotopes (deuterium and tritium) used respectively for nuclear fusion.

lead-acid battery    →   olovni akumulator

Lead-acid battery is a electrical storage device that uses a reversible chemical reaction to store energy. It was invented in 1859 by French physicist Gaston Planté. Lead-acid batteries are composed of a lead(IV) oxide cathode, a sponge metallic lead anode and a sulphuric acid solution electrolyte.

In charging, the electrical energy supplied to the battery is changed to chemical energy and stored. The chemical reaction during recharge is normally written:

In discharging, the chemical energy stored in the battery is changed to electrical energy. During discharge, lead sulfate (PbSO4) is formed on both the positive and negative plates. The chemical reaction during discharge is normally written:

Lead acid batteries are low cost, robust, tolerant to abuse, tried and tested. For higher power applications with intermittent loads however, they are generally too big and heavy and they suffer from a shorter cycle life.

solid solution    →   čvrste otopine

Solid solution is a crystalline material that is a mixture of two or more components, with ions, atoms, or molecules of one component replacing some of the ions, atoms of the other component in its normal crystal lattice.

thermoplastic    →   termoplastika

Thermoplastic is ap lastic polymer material that can be repeatedly softened through heating and hardened again by cooling. Examples are PVCor polistiren, which when heated, softens to enable moulding and welding, but on cooling hardens. If the finished product is not correct, the material can be heated and manipulated again.

thio    →   tio

Thio- is a prefix that means, replace oxygen with sulphur. For example, a sulphate ion is SO₄^2-; a thiosulphate ion is S2O₃^2-. A cyanate ion is OCN^-; a thiocyanate ion is SCN^-.

lithosphere    →   litosfera

Lithosphere (from the Greek for rocky sphere) is rigid, rocky outer layer of the Earth, consisting of the crust and the solid outermost layer of the upper mantle. The distinguishing characteristic of the lithosphere is not its composition but its flow properties. It floats on the asthenosphere, which is the heat-softened layer of the mantle below the lithosphere.

The lithospheric is not one continuous piece but is broken into about a dozen major separate rigid blocks, or plates, which move independently relative to one another. This movement of lithospheric plates over the asthenosphere is described as plate tectonics. When an oceanic plate and a continental plate meet, the heavier oceanic plate (composed mostly of basalt, specific gravity about 3.0 or peridotite, specific gravity about 3.3) subducts under the lighter continental plate (composed mostly of granite, specific gravity about 2.7).