CHEMISTRY GLOSSARY

chlorinity    →   klorinitet

Originally chlorinity (symbol Cl) was defined as the weight of chlorine in grams per kilogram of seawater after the bromides and iodides had been replaced by chlorides. To make the definition independent of atomic weights, chlorinity is now defined as 0.3285233 times the weight of silver equivalent to all the halides.

The Mohr-Knudsen titration method served oceanographers for more than 60 years to determine salinity from chlorinity. This modification of the Mohr method uses special volumetric glassware calibrated directly in chlorinity units. The Mohr method uses potassium chromate (K₂CrO₄) as an indicator in the titration of chloride ions chloride (plus a small amount of bromide and iodide) with a silver nitrate (AgNO₃) standard solution.

The other halides present are similarly precipitated.

A problem in the Mohr titration was that silver nitrate is not well suited for a primary standard. The Danish physicist Martin Knudsen (1871-1949) suggested that a standard seawater (Eau de mer Normale or Copenhagen Normal Water) be created and distributed to oceanographic laboratories throughout the world. This water was then used to standardize the silver nitrate solutions. In this way all chlorinity determinations were referred to one and the same standard which gave great internal consistency.

The relationship between chlorinity Cl and salinity S as set forth in Knudsen's tables is

In 1962, however, a better expression for the relationship between total dissolved salts and chlorinity was found to be

chromium    →   krom

Chromium was discovered by Louis-Nicholas Vauquelin (France) in 1797. The origin of the name comes from the Greek word chroma meaning colour. It is very hard, crystalline, steel-grey metal. The pure metal has a blue-white colour. It is hard, brittle and corrosion-resistant at normal temperatures. Hexavalent compounds toxic by skin contact. The most important chromium mineral is chromite [Fe,Mg(CrO₄)]. Produced commercially by heating its ore in the presence of silicon or aluminium. Used to make stainless steel. It gives the colour to rubies and emeralds. Iron-nickel-chromium alloys in various percentages yield an incredible variety of the most important metals in modern technology.

hertz    →   herc

Hertz (Hz) is the SI derived unit, with a special name, for frequency. The hertz is the frequency of a periodic phenomenon of which the period is one second (Hz = 1 s^-1). It was named after the German scientist Heinrich Hertza (1857 - 1894).

joule    →   džul

Joule (J) is the SI derived unit of energy, work, and heat. The joule is the work done when the point of application of a force of one newton is displaced a distance of one metre in the direction of the force (J = N m). The unit was named after the British scientist James Prescott Joule (1818-1889).

lipids    →   lipidi

Lipids are a loosely defined term for substances of biological origin that are soluble in nonpolar solvents. They consist of saponifiable lipids, such as glycerides (fats and oils) and phospholipids, as well as nonsaponifiable lipids, principally steroids.

cobalt    →   kobalt

Cobalt was discovered by Georg Brandt (Germany) in 1735. The origin of the name comes from the German word kobald meaning goblin or evil spirit. It is hard, ductile, lustrous bluish-grey metal. Surfaces stable in air. Reacts over time with dilute acids. It has remarkable magnetic properties. Cobalt occurs in compounds with arsenic and sulfur as in cobaltine (CoAsS) and linneite (Co₃S₄). Pure cobalt is obtained as a by-product of refining nickel, copper and iron. Used in many hard alloys; for magnets, ceramics and special glasses. Radioactive cobalt-60 is used in cancer therapy.

colloid ion    →   koloidni ion

Colloid ions emerge when colloid particles adsorb certain type of ion from solution and thus become charged with the same charge. The charge can also originate form a chemical reaction of colloid particle’s surface. Colloid ions formed by absorption of silver chloride particle can be show as follows:

Adsorbed layer is monomolecular (one molecule thick) and which type of ion will be formed depends upon which ions are present in a greater number in the solution in. Because of this colloid particles are charged with the same charge, mutual repelling occurs, and the colloid solution becomes stable. Colloid charge can be determined by electrophoresis.

copper    →   bakar

Copper has been known since ancient times. The origin of the name comes from the Latin word cuprum meaning the island of Cyprus famed for its copper mines. It is malleable, ductile, reddish-brown metal. Resistant to air and water. Exposed surfaces form greenish carbonate film. Pure copper occurs rarely in nature. Usually found in sulfides as in chalcopyrite (CuFeS₂), coveline (CuS), chalcosine (Cu₂S) or oxides like cuprite (Cu₂O). Most often used as an electrical conductor. Also used in the manufacture of water pipes. Its alloys are used in jewellery and for coins.

meitnerium    →   meitnerij

Meitnerium was discovered by Peter Armbruster, Gottfried Münzenber and their co-workers at the Heavy Ion Research Laboratory (Gesellschaft für Schwerionenforschung, GSI) in Darmstadt, Germany in 1982. Named in honour of Lise Meitner (1878-1968), the Austrian physicist. It is synthetic radioactive metal. Meitnerium was produced bybombarding bismuth-209 with iron-58.

mendelevium    →   mendelevij

Mendelevium was discovered by Albert Ghiorso, Bernard G. Harvey, Gregory R. Choppin, Stanley G. Thompson and Glenn T. Seaborg (USA) in 1955. Named in honour of Dimitri Mendeljejev, the Russian chemist who devised the periodic table. It is synthetic radioactive metal. Mendelevium was made by bombarding einsteinium with helium ions.