CHEMISTRY GLOSSARY

platinum    →   platina

Platinum was discovered by Antonio de Ulloa (South America) in 1735. The origin of the name comes from the Spanish word platina meaning silver. It is rare, very heavy, soft, silvery-white metal. Resists oxygen and water. Platinum is produced from deposits of native, or elemental. Used in jewellery, to make crucible and special containers and as a catalyst. Used with cobalt to produce very strong magnets. Also to make standard weights and measures. Resists corrosion and acid attacks except aqua regia.

plutonium    →   plutonij

Plutonium was discovered by Glenn T. Seaborg, Edwin M. McMillan, J. W. Kennedy and A. C. Wahl (USA) in 1940. Named after the planet Pluto. It is silvery-white, extremely radioactive artificially produced metal. Reacts with oxygen and acids; resists alkalis. Attacked by steam. Highly toxic. Plutonium is found rarely in some uranium ores. Made by bombarding uranium with neutrons. Used in bombs and reactors. Small quantities are used in thermo-electric generators.

poison    →   otrov

Poisons are substance, which upon contact or being introduced into an organism, impair or prevent normal metabolic processes from taking place, thus altering the normal functioning of organs or tissues.

Poisons are molecules or material that tends to collect on a catalyst surface, blocking access to active sites or destroying their activities.

Poisons are substance that can reduce a nuclear reaction by absorbing neutrons, thereby preventing more fission. If enough poisons are present in a reactor core, the chain reaction will die out.

polonium    →   polonij

Polonium was discovered by Marie Curie (Poland) in 1898. Named for Poland, native country of Marie Curie. It is silvery-grey, extremely rare, radioactive metal. Soluble in dilute acids. Highly toxic. Severe radiotoxicity. Carcinogen. Polonium occurs in pitchblende. Produced by bombarding bismuth with neutrons. Used in industrial equipment that eliminates static electricity caused by such processes as rolling paper, wire and sheet metal.

polyester    →   poliester

Polyesters are copolymers formed by condensation polymerization of dicarboxylic acid (terephthalic acid) and a dialcohol, also called a diol (ethylene glycol).

polypeptide    →   polipeptid

Polypeptides are peptides containing ten or more amino acid residues. The properties of a polypeptide are determined by the type and sequence of its constituent amino acids.

potentiometric titration    →   potenciometrijska titracija

Potentiometric titration is a volumetric method in which the potential between two electrodes is measured (referent and indicator electrode) as a function of the added reagent volume. Types of potentiometric titrations for the determination of analytes in photoprocessing solutions include acid-base, redox, precipitation, and complexometric.

Potentiometric titrations are preferred to manual titrations, since they are more accurate and precise. They are also more easily adapted to automation, where automated titration systems can process larger volumes of samples with minimal analyst involvement.

A titration curve has a characteristic sigmoid curve. The part of the curve that has the maximum change marks the equivalence point of the titration. The first derivative, ΔE/ΔV, is the slope of the curve, and the endpoint occurs at the volume, V', where ΔE/ΔV has the maximum value.

proline    →   prolin

Proline has an aliphatic side chain with a distinctive cyclic structure. It is unusual because it is conformationally restricted. The secondary amino (imino) group of proline residues is held in a rigid conformation that reduces the structural flexibility of polypeptide regions containing proline. It is not an essential amino acid, which means that the human body can synthesize it.

• Abbreviations: Pro, P
• IUPAC name: pyrrolidine-2-carboxylic acid
• Molecular formula: C₅H₉NO₂
• Molecular weight: 115.13 g/mol

protactinium    →   protaktinij

Protactinium was discovered by Otto Hahn (Germany) and Lise Meitner (Austria) in 1917. The origin of the name comes from the Greek word protos meaning first. It is very rare, silvery-white, extremely radioactive metal. Resists alkalis; reacts with oxygen and acids. Attacked by steam. Highly radiotoxic. Protactinium is extremely toxic and must be handled with great care. Protactinium does not occur in nature. Found among fission products of uranium, thorium and plutonium.

rhenium    →   renij

Rhenium was discovered by Walter Noddack, Ida Tacke and Otto Berg (Germany) in 1925. The origin of the name comes from the Latin word Rhenus meaning river Rhine. It is rare and costly, dense, silvery-white metal. Tarnishes in moist air. Resists corrosion and oxidation. Dissolves in nitric and sulfuric acids. Has a very high melting point. Rhenium is found in small amounts in gadolinite and molybdenite. Mixed with tungsten or platinum to make filaments for mass spectrographs. Its main value is as a trace alloying agent for hardening metal components that are subjected to continuous frictional forces.