CHEMISTRY GLOSSARY

supercritical fluid chromatography    →   superkritična fluidna kromatografija

Supercritical fluid chromatography (SFC) is a hybrid of gas and liquid chromatography. SFC is of importance because it permits the separation and determination of a group of compounds that are not conveniently handled by either gas or liquid chromatography. These compounds are either nonvolatile or thermally labile so that gas chromatography cannot be used and they do not contain functional groups that make possible detection by liquid chromatography. SFC has been applied to a wide variety of materials including natural prodcuts, drugs, foods, pesticides and herbicides, fossil fuels, explosives and propellants.

supercritical fluid extraction    →   superkritična fluidna ekstrakcija

Supercritical fluid extractions (SFE) have solvating powers similar to liquid organic solvents, but with higher diffusivities, lower viscosity, and lower surface tension. The main advantages of using supercritical fluids for extractions is that they are inexpensive, contaminant free, and less costly to dispose safely than organic solvents. For non-destructive isolation choose SFE, which is simply the best technology for sensitive raw materials. For these reasons supercritical carbon dioxide (scCO₂) is the reagent used to extract caffeine from coffee and tea. Its gaslike behavior allows it to penetrate deep into the green coffee beans, and it dissolves from 97 % to 99 % of the caffeine present.

thermochemical equation    →   termokemijska jednadžba

Thermochemical equation is a compact equation representing a chemical reaction that describes both the stoichiometry and the energetics of the reaction. For example, the thermochemical equation

means When one mole of gaseous methane is burned in two moles of oxygen gas, one mole of carbon dioxide gas and 2 moles of steam are produced, and 2 220 kJ of heat are released.

thorium    →   torij

Thorium was discovered by Jöns Jakob Berzelius (Sweden) in 1828. Named after Thor, the mythological Scandinavian god of war. It is heavy, grey, soft, malleable, ductile, radioactive metal. Tarnishes in air; reacts with water. Reacts violently with oxidants. Thorium is found in various minerals like monazite and thorite. Used in making strong alloys. Also in ultraviolet photoelectric cells. It is a common ingredient in high-quality lenses. Bombarded with neutrons make uranium-233, a nuclear fuel.

titanium    →   titanij

Titanium was discovered by William Gregor (England) in 1791. Named after the Titans, the sons of the Earth goddess in Greek mythology. It is shiny, dark-grey metal. Powdered form burns in air. Exposed surfaces form oxide coating. It can be highly polished and is relatively immune to tarnishing. Unreactive with alkali and most acids. Titanium usually occurs in the minerals ilmenite (FeTiO₃), rutile (TiO₂) and iron ores. Pure metal produced by heating TiO₂ with C and Cl₂ to produce TiCl₄ then heated with Mg gas in Ar atmosphere. Since it is strong and resists acids it is used in many alloys. Titanium dioxide (TiO₂), a white pigment that covers surfaces very well, is used in paint, rubber, paper and many others.

tryglyceride    →   triglicerid

Triglyceride is an ester of glycerol and three fatty acids. It is the main constituent of vegetable oil and animal fats. The fatty acids attached to the glycerol can be the same or different. Natural fatty acids found in plants and animals are typically composed only of even numbers of carbon atoms (usually from 16 to 20) due to the way they are bio-synthesized from acetyl CoA.

unsaturated fatty acid    →   nezasićena masna kiselina

Unsaturated fatty acid is a fatty acid whose carbon chain can absorb additional hydrogen atoms. Their carbon chain has one or more double or triple valence bond per molecule. The most important of these are:

ununbium    →   ununbij

Ununbium was discovered by S. Hofmann et al. collaboration at the Heavy Ion Research Laboratory (Gesellschaft für Schwerionenforschung, GSI) in Darmstadt, Germany in February 1996. The new element has not yet been officially named, but it is known as ununbium, according to the system designated by the IUPAC for naming new elements. It is synthetic radioactive metal. Using the electromagnetic velocity filter SHIP, fusion-like residues of the reaction of ⁷⁰Zn with enriched ²⁰⁸Pb targets were measured. Two chains of localized alpha-emitters were identified as originating with ²⁷⁷112 + ¹n.

ununquadium    →   ununkvadij

The discovery of ununquadium was reported informally in January 1999 following experiments towards the end of December 1998 involving scientists at Dubna (Joint Institute for Nuclear Research) in Russia and the Lawrence Livermore National Laboratory, USA. The new element has not yet been officially named, but it is known as ununquadium, according to the system designated by the IUPAC for naming new elements. It is synthetic radioactive metal. Only few atoms of element 114 (²⁸⁹114) has ever been made (through a nuclear reaction involving fusing a calcium atom with a plutonium atom) isolation of an observable quantity has never been achieved.

unununium    →   unununij

Unununium was discovered by S. Hofmann et al. collaboration at the Heavy Ion Research Laboratory (Gesellschaft für Schwerionenforschung, GSI) in Darmstadt, Germany in December 1994. The new element has not yet been officially named, but it is known as unununium, according to the system designated by the IUPAC for naming new elements. It is synthetic radioactive metal. In bombardments of ²⁰⁹Bi targets with ⁶⁴Ni using the velocity selector SHIP facility to discriminate in favor of the fused product, ²⁷²111 + ¹n, three sets of localized alpha-decay chains were observed with position-sensitive detectors.