CHEMISTRY GLOSSARY

chaos    →   kaos

Chaos is a widely diverse range of behaviour which non-linear dynamic systems exhibit under different initial conditions.

covering power    →   prekrivna moć

Covering power is the ability of a plating solution under a set of specified plating conditions to deposit metal on the surfaces of recesses or deep holes. This term suggests an ability to cover, but not necessarily to build up, a uniform coating.

environment protection    →   zaštita okoliša

From Environment protection law of the Republic of Croatia: By protection of the environment, the following is ensured: complete preservation of environment quality, natural community preservation, rational usage of natural resources and energy in the most favourable way concerning the environment as a basic condition of healthy and sustainable development.

freezing point    →   ledište

Freezing point is the temperature at which a liquid becomes a solid at normal atmospheric pressure.

See Melting point

heat of formation    →   toplina nastajanja

Heat of formation or enthalpy of is formation the heat evolved or absorbed when one mole of a compound is formed in its standard state from its constituent elements.

cadmium    →   kadmij

Cadmium was discovered by Friedrich Strohmeyer (Germany) in 1817. The origin of the name comes from the Latin word cadmia meaning calamine (zinc carbonate, ZnCO₃), or from the Greek word kadmeia with the same meaning. It is soft, malleable, blue-white metal. Tarnishes in air, soluble in acids, insoluble in alkalis. Boiling cadmium gives off a weird, yellow-colored vapour that is poisonous. Cadmium can cause a variety of health problems, including kidney failure and high blood pressure. Cadmium is obtained as a by product of zinc refining. The mayor use of cadmium is in electroplating of steel to protect it from corrosion. Also used to make nickel-cadmium batteries. The ability of cadmium to adsorb neutrons has made it of great importance in the design of nuclear reactors. Its compounds are found in paint pigments and a wide variety of intense colours.

chlorinity    →   klorinitet

Originally chlorinity (symbol Cl) was defined as the weight of chlorine in grams per kilogram of seawater after the bromides and iodides had been replaced by chlorides. To make the definition independent of atomic weights, chlorinity is now defined as 0.3285233 times the weight of silver equivalent to all the halides.

The Mohr-Knudsen titration method served oceanographers for more than 60 years to determine salinity from chlorinity. This modification of the Mohr method uses special volumetric glassware calibrated directly in chlorinity units. The Mohr method uses potassium chromate (K₂CrO₄) as an indicator in the titration of chloride ions chloride (plus a small amount of bromide and iodide) with a silver nitrate (AgNO₃) standard solution.

The other halides present are similarly precipitated.

A problem in the Mohr titration was that silver nitrate is not well suited for a primary standard. The Danish physicist Martin Knudsen (1871-1949) suggested that a standard seawater (Eau de mer Normale or Copenhagen Normal Water) be created and distributed to oceanographic laboratories throughout the world. This water was then used to standardize the silver nitrate solutions. In this way all chlorinity determinations were referred to one and the same standard which gave great internal consistency.

The relationship between chlorinity Cl and salinity S as set forth in Knudsen's tables is

In 1962, however, a better expression for the relationship between total dissolved salts and chlorinity was found to be

Le Chatelier’s principle    →   Le Chatelierov princip

The idea that a system at equilibrium will respond to a stress placed upon it in such a manner as to partially offset that stress. The principle was first stated in 1888 by the French physical chemist Henri Le Chatelier (1850-1936).

molar volume    →   molarni volumen

Molar volume is the volume occupied by substance per unit amount of substance. The volume of the gas at 0 °C and 101 325 Pa is 22.4 dm³mol^-1.

combustible    →   zapaljiv

The term combustible is often used to describe any material which will burn. However, conditions at which combustion will occur must be defined more accurately, for example a combustible liquid is 37.8 °C but below 93.3 °C. This allows a distinction to be made between combustible materials, which are fairly difficult to ignite, and flammable or highly flammable ones, which are far easier to ignite.