CHEMISTRY GLOSSARY

Born-Haber cycle    →   Born-Haberov kružni proces

Born-Haber cycle is a cycle of reactions used for calculating the lattice energies of ionic crystalline solids. For a compound MX, the lattice energy is the enthalpy of the reaction

The standard enthalpy of formation of the ionic solid is the enthalpy of the reaction

The cycle involves equating this enthalpy (which can be measured) to the sum of the enthalpies of a number of steps proceeding from the elements to the ionic solid. The steps are:

1) Atomization of the metal

2) Atomization of the nonmetal

3) Ionisation of the metal

This is obtained from the ionisation potential.

4) Ionisation of the nonmetal

This is electron affinity.

5) Formation of the ionic solids

Equation of the enthalpies gives

from which ΔH_L can be found.

cyanogen    →   cijan

Cyanogen is a colourless gas, (CN)₂ with a pungent odour. The compound is very toxic. It my be prepared in the laboratory by heating mercury (II) cyanide.

dry ice    →   suhi led

Dry ice is frozen carbon dioxide (CO₂). It is called dry ice because it sublimates, i.e. it transits to vapour without a prior transition to liquid state. It is a convenient refrigerant because it sublimes at -78 °C.

fluorescence    →   fluorescencija

Fluorescence is a luminescence phenomenon in which electron returns to it's ground state almost instantaneously (less than 10^-8 second), and in which emission from a luminescent substance ceases when the exciting source is removed. Fluorescence is characterized by radiation emission in all directions.

Carnot cycle    →   Carnotov kružni proces

Carnot cycle is the most efficient cycle of operations for a reversible heat engine. Published in 1824 by French physicist Nicolas Léonard Sadi Carnot (1796-1832), it consists of four operations on the working substance in the engine:

1-2: Isothermal expansion at thermodynamic temperature T₁ with heat Q_H taken in.

2-3: Adiabatic expansion with a fall of temperature to T₂.

3-4: Isothermal compression at temperature T₂ with heat Q_C given out.

4-1: Adiabatic compression at temperature back to T₁.

According to the Carnot principle, the efficiency of any reversible heat engine depends only on the temperature range through which it works, rather than the properties of the working substances.

cellulose    →   celuloza

Cellulose, (C₆H₁₀O₅)_n, is a polysaccharide that consists of a long unbranched chain of glucose units linked by (1→4)-β-glycoside bonds. Nature uses cellulose primarily as a structural material to impart strength and rigidity to plants. Leaves, grasses, and cotton are primarily cellulose. The fibrous nature of extracted cellulose has led to its use in textile industry for the production of cotton, artificial silk, etc. Cellulose also serves as raw material for the manufacture of cellulose acetate, known commercially as acetate rayon, and cellulose nitrate, known as guncotton. Gunncotton is the major ingredient in smokeless powder, the explosive propellant used in artillery shells and in ammunition for firearms.

freezing    →   smrzavanje

Freezing is the change of a liquid into a solid state as the temperature decreases. For water, the freezing point is 0 °C (or 273.16 K).

freezing point    →   ledište

Freezing point is the temperature at which a liquid becomes a solid at normal atmospheric pressure.

See Melting point

glass transition temperature    →   temperatura staklastog prijelaza

Glass transition temperature (T_g) is the temperature at which an amorphous polymer is transformed, in a reversible way, from a viscous or rubbery condition to a hard and relatively brittle one.

heat of fusion    →   toplina taljenja

Heat of fusion or enthalpy of fusion is the heat required to convert a substance from the solid to the liquid state with no temperature change (also called latent heat of fusion or melting).