CHEMISTRY GLOSSARY

spectroscope    →   spektroskop

Spectroscope (spectrometer) is an instrument for measuring the spectrum of light or radiation

spectroscopy    →   spektroskopija

Spectroscopy is the analysis of the lines of light emitted from excited atoms as the electrons drop back through their orbitals. These lines give the energy and distances of the electronic orbitals.

X-ray spectrum    →   spektar X-zraka

X-ray spectrum is a set of characteristic X-ray frequencies or wavelengths produced by a substance used as a target in an X-ray tube. Each element has a characteristic X-ray spectrum, and there is a strong correlation between atomic number and the frequencies of certain lines in the X-ray spectrum.

mass spectrometry    →   masena spectrometrija

Mass spectrometry is an analytical technique in which ions are separated according to the mass/charge (m/e) ratio and detected by a suitable detector.

In a mass spectrometer a sample is ionised and the positive ions produced are accelerated into a high-vacuum region containing electric and magnetic fields. These fields deflect and focus the ions onto a detector. A mass spectrum is thus obtained, consisting of a series of peaks of variable intensity to which m/e values can be assigned. Different molecules can be identified by their characteristic pattern of lines.

specific weight    →   specifična težina

Specific weight (γ) is defined as the ratio between the weight of a mass element, Δm, and the volume, ΔV, occupied by that element. As density (average) is defined as the ratio of a mass element and its volume, specific weight is equal to:

where g is gravitational acceleration.

spectrophotometer    →   spektrofotometar

Spectrophotometer is an instrument for measuring the amount of light absorbed by a sample.

The absorption of light by a substance in a solution can be described mathematically by the Beer-Lambert law

where A is the absorbance at a given wavelength of light, ε is the molar absorbtivity or extinction coefficient (L mol^-1 cm^-1), unique to each molecule and varying with wavelength, b is the length of light path through the sample (cm), and c is the concentration of the compound in solution (mol L^-1).

AAS    →   AAS

AAS is abbreviation for atomic absorption spectroscopy.

absorbance    →   apsorbancija

Absorbance (A) is a logarithm of the ratio of incident radiant power (P_o) to transmitted radiant power (P) through a sample (excluding the effects on cell walls).

The absorption of light by a substance in a solution can be described mathematically by the Beer-Lambert law

where A is the absorbance at a given wavelength of light, ε is the molar absorbtivity or extinction coefficient (L mol^-1 cm^-1), unique to each molecule and varying with wavelength, b is the length of light path through the sample (cm), and c is the concentration of the compound in solution (mol L^-1).

absorptance    →   apsorptancija

Absorptance (α) is the ratio of the radiant or luminous flux in a given spectral interval absorbed in a medium to that of the incident radiation. Also called absorption factor.

activity    →   aktivitet

Activity (a) is a thermodynamic function used in place of concentration in equilibrium constants for reactions involving nonideal gases and solutions. For the species i activity is defined as

where a_i is the activity of the species i, c_i is its molar concentration, and f_i is a dimensionless quantity called the activity coefficient.