Perfect crystal is a crystal with no defects or impurities made of completely identical repeating subunits. Further, a perfect crystal has only one possible arrangement of subunits, with every subunit making exactly the same contribution to the total energy of the crystal.
Mass (m) is the quantity of matter contained in a particle or body regardless of its location in the universe. Mass is constant, whereas weight is affected by the distance of a body from the centre of the Earth (or of other planet). The SI unit is kilogram.
According to the Einstein equation
all forms of energy possess a mass equivalent.
Nerve poison (nerve gas, agents) have had an entirely dominant role since the Second World War. Nerve poisons acquired their name because they affect the transmission of nerve impulses in the nervous system. All nerve poisons belong chemically to the group of organo-phosphorus compounds. They are stable and easily dispersed, highly toxic and have rapid effects both when absorbed through the skin and via respiration. Nerve poisons can be manufactured by means of fairly simple chemical techniques. The raw materials are inexpensive and generally readily available.
The most important nerve agents included in modern chemical weapons arsenals are:
Tabun | (o-ethyl dimethylamidophosphorylcyanide) |
Sarin | (isopropyl methylphosphonofluoridate) |
Soman | (pinacolyl methylphosphonofluoridate) |
GF | (cyclohexyl methylphosphonofluoridate) |
VX | (o-ethyl S-diisopropylaminomethyl methylphosphonothiolate) |
Nerve poisons are colorless, odorless, tasteless liquids of low volatility. Antidotes are atropine sulfate and pralidoxime iodide.
Palladium was discovered by William Hyde Wollaston (England) in 1803. Named after the asteroid Pallas which was discovered at about the same time and from the Greek name Pallas, goddess of wisdom. It is soft, malleable, ductile, silvery-white metal. Resists corrosion; dissolves in oxidizing acids. Absorbs hydrogen. Metal dust is combustible. Palladium is obtained with platinum, nickel, copper and mercury ores. Used as a substitute for silver in dental items and jewellery. The pure metal is used as the delicate mainsprings in analog wristwatches. Also used in surgical instruments and as catalyst.
Phosphorus was discovered by Hennig Brandt (Germany) in 1669. The origin of the name comes from the Greek word phosphoros meaning bringer of light. White phosphorus is white to yellow soft, waxy phosphorescent solid with acrid fumes. Toxic by inhalation, ingestion, or skin contact. Red phosphorus is powdery, non-flammable and non-toxic. Phosphorus is found most often in phosphate rock. Pure form is obtained by heating a mixture of phosphate rock, coke and silica to about 1450 °C. Used in the production of fertilizers and detergents. Some is used in fireworks, safety matches and incendiary weapons. Phosphorus is also important in the production of steels, phosphor bronze and many other products.
Radium was discovered by Marie and Pierre Curie (France) in 1898. The origin of the name comes from the Latin word radius meaning ray. It is silvery-white radioactive metal. Reacts with oxygen and water. Highly radiotoxic. Carcinogen by inhalation, ingestion, or exposure. Radium is found in uranium ores at 1 part per 3 million parts uranium. Used in treating cancer because of the gamma rays it gives off.
Radon was discovered by Friedrich Ernst Dorn (Germany) in 1900. The origin of the name is variation of the name of element radium; radon was called niton at first, from the Latin word nitens meaning shining. It is colourless, odourless radioactive, heavy, noble gas. Chemically inert and non-flammable. Highly radiotoxic. Carcinogen by inhalation. Radon is formed from the decay of radium in the earths crust. Used to treat some forms of cancer.
Transmittance (τ) is the ratio of the radiant or luminous flux at a given wavelength that is transmitted to that of the incident radiation. Also called transmission factor.
Selenium was discovered by Jöns Jakob Berzelius (Sweden) in 1817. The origin of the name comes from the Greek word selene meaning moon. It is soft metalloid similar to sulfur. Ranges from grey metallic to red glassy appearance. Unaffected by water. Soluble in alkalis and nitric acid. Burns in air. Toxic by inhalation or ingestion. Selenium is obtained from lead, copper and nickel refining. Conducts electricity when struck by light. Light causes it to conduct electricity more easily. It is used in photoelectric cells, TV cameras, xerography machines and as a semiconductor in solar batteries and rectifiers. Also colours glass red.
Silicon was discovered by Jöns Jacob Berzelius (Sweden) in 1824. The origin of the name comes from the Latin word silicis meaning flint. Amorphous form of silicon is brown powder; crystalline form has grey metallic appearance. Solid form unreactive with oxygen, water and most acids. Dissolves in hot alkali. Silica dust is a moderately toxic acute irritant. Silicon makes up major portion of clay, granite, quartz and sand. Commercial production depends on a reaction between sand (SiO2) and carbon at a temperature of around 2200 °C. Used in glass as silicon dioxide (SiO2). Silicon carbide (SiC) is one of the hardest substances known and used in polishing. Also the crystalline form is used in semiconductors.
Generalic, Eni. "Maseni udio." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
Glossary
Periodic Table