CHEMISTRY GLOSSARY

acid    →   kiselina

Acid is a type of compound that contains hydrogen and dissociates in water to produce positive hydrogen ions. The reaction for an acid HA is commonly written:

In fact, the hydrogen ion (the proton) is solvated, and the complete reaction is:

This definition of acids comes from the Arrhenius theory. Such acids tend to be corrosive substances with a sharp taste, which turn litmus red and produce colour changes with other indicators. They are referred to as protonic acids and are classified into strong acids, which are almost completely dissociated in water, (e.g. sulphuric acid and hydrochloric acid), and weak acids, which are only partially dissociated (e.g. acetic acid and hydrogen sulphide). The strength of an acid depends on the extent to which it dissociates, and is measured by its dissociation constant.

In the Lowry-Brønsted theory of acids and bases (1923), the definition was extended to one in which an acid is a proton donor (a Brønsted acid), and a base is a proton acceptor (a Brønsted base). An important feature of the Lowry-Brønsted concept is that when an acid gives up a proton, a conjugate base is formed that is capable of accepting a proton.

Similarly, every base produces its conjugate acid as a result of accepting a proton.

For example, acetate ion is the conjugate base of acetic acid, and ammonium ion is the conjugate acid of ammonia.

As the acid of a conjugate acid/base pair becomes weaker, its conjugate base becomes stronger and vice versa.

A further extension of the idea of acids and bases was made in the Lewis theory. In this, a G. N. Lewis acid is a compound or atom that can accept a pair of electrons and a Lewis base is one that can donate an electron pair. This definition encompasses "traditional" acid-base reactions, but it also includes reactions that do not involve ions, e.g.

in which NH₃ is the base (donor) and BCl₃ the acid (acceptor).

alum    →   alaun

Alums are a group of isomorphic glacial double sulphates with the general formula

where M^I can be univalent cation K, Na, Rb, Cs, NH₄ or Tl, and M^III is trivalent Al, Cr, or Fe.

amalgam    →   amalgam

Amalgams are metals alloyed with mercury. They can be solid or liquid, depending upon the mass ratio of thawed metal. Amalgam examples are gold/mercury, silver/mercury and copper/mercury all of which are used in dentistry.

americium    →   americij

Americium was discovered by Glenn T. Seaborg, Ralph A. James, Stanley G. Thompson and Albert Ghiorso (USA) in 1944. Named for the American continent. It is silvery-white, artificially produced radioactive metal. Americium was produced by bombarding plutonium with neutrons. Americium-241 is currently used in smoke detectors.

amines    →   amini

Amines are compounds formally derived from ammonia by replacing one, two, or three hydrogen atoms by hydrocarbyl groups, and having the general structures RNH₂ (primary amines), R₂NH (secondary amines), R₃N (tertiary amines). Examples are methylamine, CH₃NH₂; dimethylamine, CH₃NHCH₃; and trimethylamine, (CH₃)₃N.

actinides    →   aktinoidi

Actinides (actinons or actinoids) are the fourteen elements from thorium to lawrencium inclusive, which follow actinium in the periodic table. The position of actinium is somewhat equivocal and, although not itself an actinide, it is often included with them for comparative purpose. The series includes the following elements: thorium (Th), protactinium (Pa), uranium (U), neptunium (Np), plutonium (Pu), amercium (Am), curium (Cm), berkelium (Bk), californium (Cf), einsteinium (Es), fermium (Fm), mendelevium (Md), nobelium (No) and lawrencium (Lr). Every known isotope of the actinide elements is radioactive. Traces of Pa, Np and Pu are consequently found, but only Th and U occur naturally to any useful extent.

actinium    →   aktinij

Actinium was discovered by André Debierne (France) in 1899. The origin of the name comes from the Greek word aktinos meaning ray. It is heavy, silvery-white, very radioactive metal. Reacts with water. Glows in the dark. Actinium is extremely rare, found in all uranium ores. Usually obtained by treating radium with neutrons in a reactor.

activated charcoal    →   aktivni ugljen

Activated charcoal or activated carbon is charcoal that has been activated for adsorption by steaming or by heating in a vacuum. Charcoal is obtained by burning wood, nutshells, coconut husks or other materials. Charcoal becomes activated by heating it with steam to approximately 1000 °C in the absence of oxygen.

The chemical nature of amorphous carbon, combined with a high surface area makes it an ideal medium for the adsorption of organic chemicals. A single gram of such material can have 400 m² to 1 200 m² square meters of surface area. Activated charcoal is widely used to decolorize liquids, recover solvents, and remove toxins from water and air.

activation energy    →   energija aktivacije

Activation energy (E_a) is the energy that must be added to a system in order for a process to occur, even though the process may already be thermodynamically possible. In chemical kinetics, the activation energy is the height of the potential barrier separating the products and reactants. It determines the temperature dependence on the reaction rate.

amplitude    →   amplituda vala

Amplitude is the displacement of a wave from zero. The maximum amplitude for a wave is the height of a peak or the depth of a trough, relative to the zero displacement line.