Fractional crystallisation is a method of separating a mixture of soluble solids by dissolving them in a suitable hot solvent and then lowering the temperature slowly. The least soluble component will crystallise out first, leaving the other components in the solution. By controlling the temperature, it is sometimes possible to remove each component in turn.
Glacial acetic acid (CH3COOH) is the pure compound, as distinguished from the usual water solutions known as acetic acid. It is a colorless liquid or crystalline substance (melting point 16.6 °C) with a pungent, vinegar odor.
Copper has been known since ancient times. The origin of the name comes from the Latin word cuprum meaning the island of Cyprus famed for its copper mines. It is malleable, ductile, reddish-brown metal. Resistant to air and water. Exposed surfaces form greenish carbonate film. Pure copper occurs rarely in nature. Usually found in sulfides as in chalcopyrite (CuFeS2), coveline (CuS), chalcosine (Cu2S) or oxides like cuprite (Cu2O). Most often used as an electrical conductor. Also used in the manufacture of water pipes. Its alloys are used in jewellery and for coins.
In 1836 the British chemist John Frederic Daniell (1790-1845) proposed an improved electric cell that supplied an even current during continuous operation. Daniell cell consisted of a glass jar containing copper and zinc electrodes, each immersed in their respective acidic sulphate solutions. The two solutions were separated by a porous clay cylinder separator. It was a galvanic cell in which the spontaneous electrodissolution of zinc and electroplating of copper provided the electrical current.
Zn(s) |
→ | Zn2+ + 2e- |
+0.763 V |
Cu2+ + 2e- |
→ | Cu(s) |
+0.337 V |
Zn(s) + Cu2+ |
→← | Zn2+ + Cu(s) |
+1.100 V |
Grignard reagents are organomagnesium halides, RMgX, having a carbon- magnesium bond (or their equilibrium mixtures in solution with R2Mg + MgX2).
Heat of crystallization or enthalpy of crystallization is the heat evolved or absorbed when one mole of given substance crystallises from a saturated solution of the same substance.
Immersion plating involves depositing a metallic coating on a metal immersed in a liquid solution, without the aid of an external electric current. Also called dip plating.
Isomorphism is the existence of two or more substances that have the same crystal structure, so that they form solid solutions.
Manganometry is a quantitative oxidimetric method based on measurement of potassium permanganate (KMnO4) spent for an oxidation of the matter in question.
Dialysis is a method by which large molecules (such as starch or protein) and small molecules (such as glucose or amino acids) may be separated in a solution by selective diffusion through a semipermeable membrane. Through this kind of membrane dissolved particles pass and colloid dimension particles fall behind. For example, if a mixed solution of starch and glucose is placed in a closed container made of a semipermeable substance (such as cellophane), which is then immersed in a beaker of water, the smaller glucose molecules will pass trough the membrane into the water, while the starch molecules remain behind.
Generalic, Eni. "Koncentrirana otopina." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
Glossary
Periodic Table