CHEMISTRY GLOSSARY
Born-Haber cycle → Born-Haberov kružni proces
Born-Haber cycle is a cycle of reactions used for calculating the lattice energies of ionic crystalline solids. For a compound MX, the lattice energy is the enthalpy of the reaction
The standard enthalpy of formation of the ionic solid is the enthalpy of the reaction
The cycle involves equating this enthalpy (which can be measured) to the sum of the enthalpies of a number of steps proceeding from the elements to the ionic solid. The steps are:
1) Atomization of the metal
2) Atomization of the nonmetal
3) Ionisation of the metal
This is obtained from the ionisation potential.
4) Ionisation of the nonmetal
This is electron affinity.
5) Formation of the ionic solids
Equation of the enthalpies gives
from which ΔHL can be found.
boron → bor
Boron compounds have been known for thousands of years, but the element was not discovered until 1808 by Sir Humphry Davy (England) and independently by Joseph-Louis Gay-Lussac (France) and L. J. Thenard (France). The origin of the name comes from the Arabic word buraq and the Persian word burah meaning boraks. It is hard, brittle, lustrous black semimetal. Unreactive with oxygen, water, alkalis or acids. Combines with most metals to form borides. Boron is obtained from kernite, a kind of borax (Na2B4O7·10H2O). High purity boron is produced by electrolysis of molten potassium fluroborate and potassium chloride (KCl). Amorphous boron is used in pyrotechnic flares to provide a distinctive green color and in rockets as an igniter.
chemiluminescence → kemiluminiscencija
Chemiluminescence is energy release in form of electromagnetic radiation during a chemical reaction.
chemisorption → kemisorpcija
Chemisorption is a binding of a liquid or gas on the surface or in the interior of a solid by chemical bonds or forces.
chemotherapy → kemoterapija
Chemotherapy is the treatment of disease by means of chemicals that have a specific toxic effect upon the disease producing microorganisms (antibiotics) or that selectively destroy cancerous tissue (anticancer therapy).
calorimeter → kalorimetar
Calorimeter is an instrument used to measure the energy absorbed or released in a chemical reaction. It also used in determining specific heat.
catalyst → katalizator
Catalyst is a substance that increases the rate of a chemical reaction without itself undergoing any permanent chemical change. Catalysts that have the same phase as the reactants are homogenous catalysts (e.g. enzymes in biochemical reactions). Those that have a different phase are heterogeneous catalyst (e.g. metals or oxides used in gas reactions).
The catalyst provides an alternative pathway by which the reaction can proceed, in which the activation energy is lower. In thus increases the rate at which the reaction comes to an equilibrium, although it does not alter the position of the equilibrium.
cellulose → celuloza
Cellulose, (C6H10O5)n, is a polysaccharide that consists of a long unbranched chain of glucose units linked by (1→4)-β-glycoside bonds. Nature uses cellulose primarily as a structural material to impart strength and rigidity to plants. Leaves, grasses, and cotton are primarily cellulose. The fibrous nature of extracted cellulose has led to its use in textile industry for the production of cotton, artificial silk, etc. Cellulose also serves as raw material for the manufacture of cellulose acetate, known commercially as acetate rayon, and cellulose nitrate, known as guncotton. Gunncotton is the major ingredient in smokeless powder, the explosive propellant used in artillery shells and in ammunition for firearms.
Citing this page:
Generalic, Eni. "Kompjutacijska kemija." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
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