Mercury has been known since ancient times. The origin of the name comes from the Latin word hydrargyrum meaning liquid silver. It is heavy, silver-white metal, liquid at ordinary temperatures. Stable in air and water. Unreactive with alkalis and most acids. Gives off poisonous vapour. Chronic cumulative effects. Mercury only rarely occurs free in nature. The chief ore is cinnabar or mercury sulfide (HgS). Used in thermometers, barometers and batteries. Also used in electrical switches and mercury-vapour lighting products.
Minerals are compounds in which metals can be found in nature. Metals in nature can appear as:
autochthonous | Au, Cu, Pt, Ag, Pd, Hg, Ir |
oxides | Fe, Al, Sn, Cr, Mn, W, Cu |
sulphides | Cu, Pb, Zn, Ni, Ag, Co, Sb, Hg, Mo, Cd, Bi |
carbonates | Fe, Zn, Cu, Mg, Mn, Pb |
silicates | Ni, Cu, Zn, Mn |
chlorides | Ag, Cu, Mg, Na, K |
sulphates | Ca, Ba, Sr, Cu |
Mustard agents are usually classified as blistering agents owing to the similarity of the wounds caused by these substances resembling burns and blisters. However, since mustard agents also cause severe damage to the eyes, respiratory system and internal organs, they should preferably be described as blistering and tissue-injuring agents. Normal mustard agent (yperite), 1,1-thio-bis-[2-chloroethane], reacts with a large number of biological molecules. The effect of mustard agent is delayed and the first symptoms do not occur between 2-24 hours after exposure. At room temperature, mustard agent is a liquid with low volatility and is very stable during storage.
Osmium was discovered by Smithson Tennant (England) in 1803. The origin of the name comes from the Greek word osme meaning smell. It is hard fine black powder or hard, lustrous, blue-white metal. Unaffected by air, water and acids. Characteristic acrid, chlorine like odour due to tetroxide compound. Osmium tetroxide highly toxic. Osmium is obtained from the same ores as platinum. Used to tip gold pen points, instrument pivots, to make electric light filaments. Used for high temperature alloys and pressure bearings. Very hard and resists corrosion better than any other.
Photochemical reactions are those reactions which are conducted under the influence of light that is under the influence of ultraviolet, visible and infrared part of the light spectrum. Some systems can be influenced only by radiation that is absorbed by that system. Photochemical reactions are for example photosynthesis, creation of photography, generation of phosgene, creation of hydrochloride etc.
Plasma is a highly ionised gas in which the charge of the electrons is balanced by the charge of the positive ions, so that the system as a whole is electrically neutral. Plasmas are created by exposing gases at low pressure to an electric or electromagnetic field. In semiconductor processing, plasmas are used for etching and thin film deposition (the excited state of the gas makes it very reactive). In everyday life plasmas are used to give light in fluorescent light bulbs, neon lamps, and blue insect traps.
Polymerization is a reaction of connecting many monomers in one long molecule whereby polymers are created.
Practical salinity SP is defined on the Practical Salinity Scale of 1978 (PSS-78) in terms of the conductivity ratio K15 which is the electrical conductivity of the sample at temperature t68 = 15 °C and pressure equal to one standard atmosphere, divided by the conductivity of a standard potassium chloride (KCl) solution at the same temperature and pressure. The mass fraction of KCl in the standard solution is 0.0324356 (32.4356 g of KCl in 1 kg of solution). When K15 = 1, the Practical Salinity P S is by definition 35. The conductivity of that reference solution is C(35,1568,0) = 42.914 mS/cm = 4.2914 S/m (Siemens per meter). Note that Practical Salinity is a unit-less quantity. Though sometimes convenient, it is technically incorrect to quote Practical Salinity in "psu". When K15 is not unity, SP and K15 are related by the PSS-78 equation
At a temperature of t68 = 15 °C, Rt is simply K15 and Practical Salinity SP can be determined from the above equation. For temperatures other than t68 = 15 °C, Practical Salinity SP is given by the following function of Rt (k = 0.0162)
Referent electrode is an electrode whose potential is known and completely independent of analyte concentration. Mostly used referent electrodes are calomel and silver/silver chloride electrode.
Table: Dependence of referent electrodes potentials on KCl concentration
Potential vs. SHE / V | |||||
calomel electrode | Ag/AgCl electrode | ||||
t / °C | 0.1 mol dm-3 | 3.5 mol dm-3 | sat. solution | 3.5 mol dm-3 | sat. solution |
15 | 0.3362 | 0.254 | 0.2511 | 0.212 | 0.209 |
20 | 0.3359 | 0.252 | 0.2479 | 0.208 | 0.204 |
25 | 0.3356 | 0.250 | 0.2444 | 0.205 | 0.199 |
30 | 0.3351 | 0.248 | 0.2411 | 0.201 | 0.194 |
35 | 0.3344 | 0.246 | 0.2376 | 0.197 | 0.189 |
Rhenium was discovered by Walter Noddack, Ida Tacke and Otto Berg (Germany) in 1925. The origin of the name comes from the Latin word Rhenus meaning river Rhine. It is rare and costly, dense, silvery-white metal. Tarnishes in moist air. Resists corrosion and oxidation. Dissolves in nitric and sulfuric acids. Has a very high melting point. Rhenium is found in small amounts in gadolinite and molybdenite. Mixed with tungsten or platinum to make filaments for mass spectrographs. Its main value is as a trace alloying agent for hardening metal components that are subjected to continuous frictional forces.
Generalic, Eni. "Klor." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
Glossary
Periodic Table