CHEMISTRY GLOSSARY

composition of ocean water    →   sastav oceanske vode

The proportions of the major constituents of ocean water are almost constant throughout the world. Salinity (total salt content) and the concentrations of individual chemical constituents in sea wateris given the units psu (practical salinity units). For most purposes one can assume that the new unit, psu, and the older unit, ‰, are synonymous.

The average composition of the ocean water is as shown on the following table.

Zimmermann-Reinhardt’s reagent    →   Zimmermann-Reinhardtov reagens

Zimmermann-Reinhardt’s reagent is a mixture of manganese(II) sulphate, sulphuric acid and phosphorus acid. It is used for preventing oxidation of chloride ion while titrating iron(II) ion with permanganate solution.

copper    →   bakar

Copper has been known since ancient times. The origin of the name comes from the Latin word cuprum meaning the island of Cyprus famed for its copper mines. It is malleable, ductile, reddish-brown metal. Resistant to air and water. Exposed surfaces form greenish carbonate film. Pure copper occurs rarely in nature. Usually found in sulfides as in chalcopyrite (CuFeS₂), coveline (CuS), chalcosine (Cu₂S) or oxides like cuprite (Cu₂O). Most often used as an electrical conductor. Also used in the manufacture of water pipes. Its alloys are used in jewellery and for coins.

desiccator    →   eksikator

Desiccator is a glass container with dry atmosphere due to the presence of some dehydrating agent. It is used for protecting the samples, reagents or precipitates from humidity. As dehydrating agent usually waterless calcium chloride (CaCl₂) is used.

dipole    →   dipol

Dipole is a pair of separated opposite electric charges. Electric dipole is an assemblage of atoms or subatomic particles having equal electric charges of opposite sign separated by a finite distance. In the case of HCl, the electrons are attracted towards the more electronegative chlorine atom.

dry cell    →   suhi članak

Dry cell or Leclanche cell is a primary cell having a zinc anode, a carbon (graphite) cathode surrounded by manganese dioxide, and a paste containing ammonium chloride as electrolyte. The electromotive force (emf) produced by a dry cell is 1.5 V. Dry cell is not reversible and therefore have a limited operating life. It is invented by the French engineer Georges Leclanché (1839.-1882.) in 1866.

electrode of the second kind    →   elektroda drugog reda

Electrodes of the second kind are metal electrodes assembly with the equilibrium potential being a function of the concentration of an anion in the solution. Typical examples are the silver/silver-chloride electrode and the calomel electrode. The potential of the metal is controlled by the concentration of its cation in the solution, but this, in turn, is controlled by the anion concentration in the solution through the solubility product of the slightly soluble metal salt. Contrast with electrode of the first kind and electrode of the third kind.

electronegativity    →   elektronegativnost

Electronegativity is a parameter originally introduced by L. Pauling which describes, on a relative basis, the power of an atom to attract electrons. For example, in hydrogen chloride, the chlorine atom is more electronegative than the hydrogen and the molecule is polar, with a negative charge on the chlorine atom.

There are various ways of assigning values for the electronegativity of an element. Pauling electronegativities are based on bond dissociation energies using a scale in which fluorine, the most electronegative element, has the value 4 and francium, the lowest electronegative element, has the value 0.7.

filter paper    →   filtar papir

Filter paper is a quantitative paper used for filtering and made of pure cellulose treated with hydrochloric and hydrofluoric acid. This kind of paper burns out practically without any remains (less than 0.0001 g ashes). Different types of paper are marked with numbers; qualitative bears marking 595 or 597 and quantitative 589 or 590. Dependable upon precipitate character, different types of filter paper are used:

• black band (589¹) - 100 mL of fluid flows through it in 20 s to 30 s. It is used for filtering of gelatinous precipitates.
• white band (589²) - 100 mL of fluid flows through it in 40 s to 60 s. It is used for coarse crystalline precipitates filtration.
• blue band (589³) - 100 mL of fluid flows through it in 200 s to 400 s. It is used for fine crystalline precipitates.

freon    →   freon

Freon (chlorofluorocarbon, CFC) a type of compound in which some or all of the hydrogen atoms of hydrocarbon (usually an alkane) have been replaced by chlorine and fluorine atoms. Most CFC are chemically uncreative and are stable at high temperatures. They are used as aerosol propellants, refrigerants, and solvents, and in the manufacture of rigid packaging foam. CFC because of their chemical inertness, can diffuse unchanged into the upper atmosphere. Here, photochemical reactions cause them to break down and react with ozone. For his reason, their use has been discouraged.