CHEMISTRY GLOSSARY

Winkler’s method    →   Winklerova metoda

Winkler’s method was once a common method used to determine the dissolved oxygen concentration by titration. Now rarely used due to the accuracy and low price of oxygen meters.

The water sample is first treated with excess manganese(II) sulfate solution and then with an alkaline solution of potassium iodide. The Mn(OH)₂ initially formed reacts with the dissolved oxygen. The amount of MnO(OH)₂ formed is determined by reaction with iodide ion in acidic solution. The iodine formed may be titrated against standard thiosulfate solution, using starch as an indicator.

yttrium    →   itrij

Yttrium was discovered by Carl Gustaf Mosander (Sweden) in 1843. Named after Ytterby, a village in Sweden. It is silvery, ductile, fairly reactive metal. Exposed surfaces form oxide film. Easily combustible, reacts with oxygen in water to release hydrogen. Yttrium is found in minerals such as monazite, xenotime and yttria. Combined with europium to make red phosphors for colour TV’s. Yttrium oxide and iron oxide combine to form a crystal garnet used in radar.

zeolite    →   zeolit

Zeolite is a natural or synthetic hydrated aluminosilicate with an open three-dimensional crystal structure, in which water molecules are held in cavites in the latice. The water can be driven off by heating and the zeolite can then absorb other molecules of suitable size. Zeolites are used for separating mixtures by selective absorption.

zirconium    →   cirkonij

Zirconium was discovered by Martin Heinrich Klaproth (Germany) in 1789. The origin of the name comes from the Arabic word zargun meaning gold colour. It is grey-white, lustrous, corrosion-resistant metal. Exposed surfaces form oxide protective film. Zirconium is found in many minerals such as zircon and baddeleyite. Used in alloys such as zircaloy this is used in nuclear applications since it does not readily absorb neutrons. Also baddeleyite is used in lab crucibles. Used in high-performance pumps and valves. Clear zircon (ZrSiO₄) is a popular gemstone.