CHEMISTRY GLOSSARY

chemical compound formula    →   formula kemijskog spoja

Chemical elements are represented by their symbols, and chemical compounds are represented by a group of symbols of those elements from which the compound is composed. That group of symbols, which shows which atoms and in which number relation they are present in certain compound is called a chemical compound formula.

In a formula chemical symbols show which element is present in a certain compound, and its index shows how much of that element there is in a certain compound. From sulphuric acid formula H₂SO₄ we can see that one molecule of sulphuric acid consists of two atoms of hydrogen, one atom of sulphur and four atoms of oxygen.

chromium    →   krom

Chromium was discovered by Louis-Nicholas Vauquelin (France) in 1797. The origin of the name comes from the Greek word chroma meaning colour. It is very hard, crystalline, steel-grey metal. The pure metal has a blue-white colour. It is hard, brittle and corrosion-resistant at normal temperatures. Hexavalent compounds toxic by skin contact. The most important chromium mineral is chromite [Fe,Mg(CrO₄)]. Produced commercially by heating its ore in the presence of silicon or aluminium. Used to make stainless steel. It gives the colour to rubies and emeralds. Iron-nickel-chromium alloys in various percentages yield an incredible variety of the most important metals in modern technology.

glyceride    →   glicerid

Glycerides are esters of glycerol (propane-1,2,3-triol) with fatty acids, widely distributed in nature. They are by a long-established custom subdivided into triglycerides, 1,2- or 1,3-diglycerides, and 1- or 2- monoglycerides, according to the number and positions of acyl groups.

Lewis, Gilbert N.    →   Lewis, Gilbert N.

Gilbert Newton Lewis (1875-1946) is an American chemist whose theory of the electron pair fostered understanding of the covalent bond and extended the concept of acids and bases.

chlorinity    →   klorinitet

Originally chlorinity (symbol Cl) was defined as the weight of chlorine in grams per kilogram of seawater after the bromides and iodides had been replaced by chlorides. To make the definition independent of atomic weights, chlorinity is now defined as 0.3285233 times the weight of silver equivalent to all the halides.

The Mohr-Knudsen titration method served oceanographers for more than 60 years to determine salinity from chlorinity. This modification of the Mohr method uses special volumetric glassware calibrated directly in chlorinity units. The Mohr method uses potassium chromate (K₂CrO₄) as an indicator in the titration of chloride ions chloride (plus a small amount of bromide and iodide) with a silver nitrate (AgNO₃) standard solution.

The other halides present are similarly precipitated.

A problem in the Mohr titration was that silver nitrate is not well suited for a primary standard. The Danish physicist Martin Knudsen (1871-1949) suggested that a standard seawater (Eau de mer Normale or Copenhagen Normal Water) be created and distributed to oceanographic laboratories throughout the world. This water was then used to standardize the silver nitrate solutions. In this way all chlorinity determinations were referred to one and the same standard which gave great internal consistency.

The relationship between chlorinity Cl and salinity S as set forth in Knudsen's tables is

In 1962, however, a better expression for the relationship between total dissolved salts and chlorinity was found to be

cobalt    →   kobalt

Cobalt was discovered by Georg Brandt (Germany) in 1735. The origin of the name comes from the German word kobald meaning goblin or evil spirit. It is hard, ductile, lustrous bluish-grey metal. Surfaces stable in air. Reacts over time with dilute acids. It has remarkable magnetic properties. Cobalt occurs in compounds with arsenic and sulfur as in cobaltine (CoAsS) and linneite (Co₃S₄). Pure cobalt is obtained as a by-product of refining nickel, copper and iron. Used in many hard alloys; for magnets, ceramics and special glasses. Radioactive cobalt-60 is used in cancer therapy.

lipase    →   lipaza

Lipase is an enzyme, secreted by the pancreas and the glands of the small intestine that breaks down fats into glycerol and fatty acids during digestion.

methanoate    →   metaonat

Methanoate (formate) is a salt of methanic (formic) carboxyl acid.

Millon’s reaction    →   Millonova reakcija

Millon’s reaction is used for testing proteins by the appearance of red colour which the proteins give by reacting with a solution of mercury in nitric acid.

coenzyme a    →   koenzim a

Coenzyme A (CoA) is an essential metabolic cofactor synthesized from cysteine, pantothenate (vitamin B5), and ATP. CoA plays important roles in many metabolic pathways, including the tricarboxylic acid (TCA) cycle, and the synthesis and oxidation of fatty acids. One of the main functions of CoA is the carrying and transfer of acyl groups. Acylated derivatives (acetyl-CoA) are critical intermediates in many metabolic reactions.