CHEMISTRY GLOSSARY

chemiluminescence    →   kemiluminiscencija

Chemiluminescence is energy release in form of electromagnetic radiation during a chemical reaction.

chemisorption    →   kemisorpcija

Chemisorption is a binding of a liquid or gas on the surface or in the interior of a solid by chemical bonds or forces.

chemotherapy    →   kemoterapija

Chemotherapy is the treatment of disease by means of chemicals that have a specific toxic effect upon the disease producing microorganisms (antibiotics) or that selectively destroy cancerous tissue (anticancer therapy).

chlorofluorocarbons    →   klorofluorougljici

Chlorofluorocarbons (CFC) are manmade chemicals containing chlorine, fluorine, and carbon. CFCs are used for industrial purposes and in the home for refrigeration, air conditioning, aerosols and as a raw material in polystyrene production.

Born-Haber cycle    →   Born-Haberov kružni proces

Born-Haber cycle is a cycle of reactions used for calculating the lattice energies of ionic crystalline solids. For a compound MX, the lattice energy is the enthalpy of the reaction

The standard enthalpy of formation of the ionic solid is the enthalpy of the reaction

The cycle involves equating this enthalpy (which can be measured) to the sum of the enthalpies of a number of steps proceeding from the elements to the ionic solid. The steps are:

1) Atomization of the metal

2) Atomization of the nonmetal

3) Ionisation of the metal

This is obtained from the ionisation potential.

4) Ionisation of the nonmetal

This is electron affinity.

5) Formation of the ionic solids

Equation of the enthalpies gives

from which ΔH_L can be found.

boron    →   bor

Boron compounds have been known for thousands of years, but the element was not discovered until 1808 by Sir Humphry Davy (England) and independently by Joseph-Louis Gay-Lussac (France) and L. J. Thenard (France). The origin of the name comes from the Arabic word buraq and the Persian word burah meaning boraks. It is hard, brittle, lustrous black semimetal. Unreactive with oxygen, water, alkalis or acids. Combines with most metals to form borides. Boron is obtained from kernite, a kind of borax (Na₂B₄O₇·10H₂O). High purity boron is produced by electrolysis of molten potassium fluroborate and potassium chloride (KCl). Amorphous boron is used in pyrotechnic flares to provide a distinctive green color and in rockets as an igniter.

computational chemistry    →   kompjutacijska kemija

Computational chemistry is a branch of chemistry concerned with the prediction or simulation of chemical properties, structures, or processes using numerical techniques.

congener    →   srodnost

Congener is a term in chemistry that refers to one of many variants or configurations of a common chemical structure. Elements belonging to the same group on the periodic table. For example, sodium and potassium are congeners.

cyanogen    →   cijan

Cyanogen is a colourless gas, (CN)₂ with a pungent odour. The compound is very toxic. It my be prepared in the laboratory by heating mercury (II) cyanide.

decomposing    →   raščinjavanje

Decomposing in analytical chemistry means that a certain substance is converted, by melting it with a suitable melting medium (sodium carbonate, sodium hydroxide, sodium peroxide, ...) in the kind of compound which will afterwards that dissolve in water, acid or base very easily.