CHEMISTRY GLOSSARY

argon    →   argon

Argon was discovered by Lord Raleigh and Sir William Ramsay (Scotland) in 1894. The origin of the name comes from the Greek word argos meaning inactive. It is colourless and odourless noble gas. Chemically inert. It is the third most abundant element in the earth’s atmosphere and makes up about 1 %. Argon is continuously released into the air by decay of radioactive potassium-40. Pure form is obtained from fractional distillation of liquid air. Used in lighting products. It is often used in filling incandescent light bulbs. Some is mixed with krypton in fluorescent lamps. Crystals in the semiconductor industry are grown in argon atmospheres.

aromatic compounds    →   aromatski ugljikovodici

Aromatic compounds are a major group of unsaturated cyclic hydrocarbons containing one or more rings, typified by benzene, which has a 6-carbon ring containing three double bonds. All the bonds in benzene (C₆H₆) are the same length intermediate between double and single C-C bonds. The properties arise because the electrons in the p-orbitals are delocalised over the ring, giving extra stabilization energy of 150 kJ/mol over the energy of Kekulé structure. Aromatic compounds are unsaturated compounds, yet they do not easily partake in addition reactions.

Historical use of the term implies a ring containing only carbon (e.g., benzene, naphthalene), but it is often generalized to include heterocyclic structures such as pyridine and thiophene.

asbestos    →   azbest

Asbestos is any one of a group of fibrous amphibole minerals (from the silicate group). It has widespread commercial uses because of its resistance to heat, chemical inertness., and high electrical resistance. Since 1970s short asbestos fibres have been recognized as a cause of asbestosis, a serious lung disorder, and mesothelioma, a fatal form of lung cancer. These concerns have limited its use and imposed many safety procedures when it is used.

astatine    →   astat

Astatine was discovered by Emilio Gino Segrè, Dale R. Corson and K. R. MacKenzie (USA) in 1940. The origin of the name comes from the Greek word astatos meaning unstable. It is unstable, radioactive member of the halogen group. Astatine does not occur in nature. Similar to iodine. Produced by bombarding bismuth with alpha particles. Since its isotopes have such short half-lives there are no commercially significant compounds of astatine.

atom    →   atom

Atom is an atom is the smallest particle of an element that retains the chemical properties of the element. Rutherford-Bohr’s model represents the atom as a positively charged core of a size around 10^-14 m composed of protons (positive particles) and neutrons (neutral particles) around which negatively charged electrons circle. The number of protons and electrons are equal, so the atom is an electrically a neutral particle. Diameter of the atom is about 10^-10 m.

chemisorption    →   kemisorpcija

Chemisorption is a binding of a liquid or gas on the surface or in the interior of a solid by chemical bonds or forces.

chemotherapy    →   kemoterapija

Chemotherapy is the treatment of disease by means of chemicals that have a specific toxic effect upon the disease producing microorganisms (antibiotics) or that selectively destroy cancerous tissue (anticancer therapy).

complete ionic equation    →   potpuna ionska jednadžba

Complete ionic equation is a balanced equation that describes a reaction occurring in a solution, in which all strong electrolytes are written as dissociated ions.

autocatalysis    →   autokataliza

Autocatalysis is a reaction in which its product can act as a catalyst. Oxalate oxidation with permanganate in an acid solution is a slow reaction

Mn²⁺-ions catalyse this reaction. When enough Mn²⁺-ions are created, the reaction occurs instantly.

base    →   baza

Historically, base is a substance that yields an OH - ion when it dissociates in solution, resulting in a pH>7. In the Brønsted definition, a base is a substance capable of accepting a proton in any type of reaction. The more general definition, due to G.N. Lewis, classifies any chemical species capable of donating an electron pair as a base. Typically, bases are metal oxides, hydroxides, or compounds (such as ammonia) that give hydroxide ions in aqueous solution.