CHEMISTRY GLOSSARY

heat of reaction    →   toplina kemijske reakcije

Heat of reaction or enthalpy of reaction is the heat evolved or absorbed as a result of the complete chemical reaction of molar amounts of the reactants.

Clapeyron equation    →   Clapeyronova jednadžba

Clapeyron equation (also called the Clausius-Clapeyron equation) is a relation between pressure and temperature of two phases of a pure substance that are in equilibrium,

where Δ_trsS is the difference in entropy between the phases and Δ_trsV the corresponding difference in volume.

ideal gas law    →   jednadžba stanja idealnog plina

The generalized ideal gas law is derived from a combination of the laws of Boyle and Charles. Ideal gas law is the equation of state

which defines an ideal gas, where p is pressure, V molar volume, T temperature, and R the molar gas constant (8.314 JK^-1mol^-1).

Schrodinger equation    →   Schrodingerova jednadžba

Schrödinger equation is the basic equation of wave mechanics which, for systems not dependent on time, takes the form:

where Ψ is the wavefunction, V is the potential energy expressed as a function of the spatial coordinates, E its total energy, ² is the Laplacian operator, h is Planck’s constant, and m is the mass.

van der Waals’ equation    →   van der Waalsova jednadžba

Van der Waals’ equation is an equation of state for real fluids which takes the form:

where p is pressure, V_m is molar volume, T is temperature, R is the molar gas constant, and a and b are characteristic parameters of the substance which describe the effect of attractive and repulsive intermolecular forces.

acylaction reaction    →   reakcije aciliranja

Acylaction reaction involves the introduction of an acyl group (RCO-) into a compound. An alkyl halide is reacted with an alcohol or a carboxylic acid anhydride e.g.

The introduction of an acetyl group (CH₃CO-) is acetylation, a process used for protecting -OH groups in organic synthesis.

chemical equation equalization    →   izjednačavanje kemijske jednadžbe

Chemical equation equalization is determining values of stechiometric coefficients of reactants and products in a chemical equation in a way that the number of atoms of each element is equal before and after the reaction.

chemical reaction    →   kemijska reakcija

Chemical reaction is a change of chemical properties of substances which react with each other. By means of a chemical reaction new substances are created by bond breaking between atoms and molecules of reactants and their reuniting in a new way, thereby creating products. Chemical reactions can be shown by chemical equations.

elementary reaction    →   elementarna reakcija

Elementary reaction is a reaction that occurs in a single step. Equations for elementary reactions show the actual molecules, atoms, and ions that react on a molecular level.

chain reaction    →   lančana reakcija

Chain reaction is a reaction done in three steps: initiation in which usually radicals are made which react with other molecules in stage of propagation and, when all reactants are spent, it ends by termination when all available radicals are completely spent.

Nuclear chain reaction refers to a process in which neutrons released in fission produce an additional fission in at least one further nucleus. Nuclear power plants operate by precisely controlling the rate at which nuclear reactions occur. On the other hand, nuclear weapons are specifically engineered to produce a reaction that is so fast and intense it cannot be controlled after it has started.