CHEMISTRY GLOSSARY

equation of state    →   jednadžba stanja

Equation of state is an equation relating the pressure, volume, and temperature of a substance or system. Equation of state for ideal gas

where p is pressure, V molar volume, T temperature, and R the molar gas constant (8.314 JK^-1mol^-1).

colloid    →   koloid

Colloids are systems in which there are two or more phases, with one (the dispersed phase) distributed in the other (the continuous phase). Moreover, at least one of the phases has small dimensions, in the range between 1 nm and 1 μm (10^-9 m – 10^-6 m). Dimension, rather than the nature of the material, is characteristic. In this size range, the surface area of the particle is large with respect to its volume so that unusual phenomena occur, e.g., the particles do not settle out of the suspension by gravity and are small enough to pass through filter membranes. Macromolecules (proteins and other high polymers) are at the lower limit of this range; the upper limit is usually taken to be the point at which the particles can be resolved in an optical microscope.

Colloidal particles may be gaseous, liquid, or solid, and occur in various types of suspensions:

Sols - dispersions of small solid particles in a liquid.

Emulsions - colloidal systems in which the dispersed and continuous phases are both liquids.

Gels - colloids in which both dispersed and continuous phases have a three-dimensional network throughout the material.

Aerosols - colloidal dispersions of liquid or solid particles in a gas.

Foams - dispersions of gases in liquids or solids.

colloid ion    →   koloidni ion

Colloid ions emerge when colloid particles adsorb certain type of ion from solution and thus become charged with the same charge. The charge can also originate form a chemical reaction of colloid particle’s surface. Colloid ions formed by absorption of silver chloride particle can be show as follows:

Adsorbed layer is monomolecular (one molecule thick) and which type of ion will be formed depends upon which ions are present in a greater number in the solution in. Because of this colloid particles are charged with the same charge, mutual repelling occurs, and the colloid solution becomes stable. Colloid charge can be determined by electrophoresis.

complexometry    →   kompleksometrija

Complexometry is a volumetric analytic method which is based on titration of metal ion solutions with a substance that, combined with metal ions yields complex compounds, e.g. EDTA. The stoichiometric ratio of EDTA-metal in complexometric analyses is always 1:1, whatever the valency of the metal

eutectic    →   eutektik

Eutectic is a solid solution consisting of two or more substances and having the lowest freezing point of any possible mixture of these components.

Eutectic point is the lowest temperature at which the eutectic mixture can exist in a liquid phase. A liquid having the eutectic composition will freeze at a single temperature without a change of composition.

fraction    →   udio

Fraction is a ratio of two quantities of the same kind, the numerator quantity applying to one constituent (or part) of the system and the denominator to the sum of quantities for all constituents (parts) of the system. When applied to mixtures fractions represent a group of three quantities: mass fraction, volume fraction and amount fraction (or mole fraction equal to the number fraction).

fractional crystallisation    →   frakcijska kristalizacija

Fractional crystallisation is a method of separating a mixture of soluble solids by dissolving them in a suitable hot solvent and then lowering the temperature slowly. The least soluble component will crystallise out first, leaving the other components in the solution. By controlling the temperature, it is sometimes possible to remove each component in turn.

composition of ocean water    →   sastav oceanske vode

The proportions of the major constituents of ocean water are almost constant throughout the world. Salinity (total salt content) and the concentrations of individual chemical constituents in sea wateris given the units psu (practical salinity units). For most purposes one can assume that the new unit, psu, and the older unit, ‰, are synonymous.

The average composition of the ocean water is as shown on the following table.

concentration    →   koncentracija

1. Group of four quantities characterizing the composition of a mixture with respect to the volume of the mixture (mass, amount, volume and number concentration).

2. Short form for amount (of substance) concentration (substance concentration in clinical chemistry).

conditional electrode potential    →   uvjetni elektrodni potencijal

Conditional or formal electrode potential (E°’) is equal to electrode potential (E) when overall concentrations of oxidised and reduced form in all its forms in a solution are equal to one. Conditional electrode potential includes all effects made by reactions that do not take part in the electron exchange, but lead to change of ion power, changes of pH, hydrolysis, complexing, precipitating, etc.

At 298 K (25 °C) and by converting natural (Napierian) logarithms into decimal (common, or Briggian) logarithms, Nernst’s equation for electrode potential can be written as follows: