CHEMISTRY GLOSSARY

gravimetry    →   gravimetrija

Gravimetry is the quantitative measurement of an analyte by weighing a pure, solid form of the analyte. Since gravimetric analysis is an absolute measurement, it is the principal method for analysing and preparing primary standards.

A typical experimental procedure to determine an unknown concentration of an analyte in a solution is as follows:

- quantitatively precipitate the analyte from the solution

- collect the precipitate by filtering and wash it to remove impurities

- dry the solid in an oven to remove the solvent

- weigh the solid on an analytical balance

- calculate the analyte concentration in the original solution based on the weight of the precipitate.

manganese    →   mangan

Manganese was discovered by Johann Gahn (Sweden) in 1774. The origin of the name comes from the Latin word magnes meaning magnet, or magnesia nigri meaning black magnesia (MnO₂). It is hard, brittle, grey-white metal with a pinkish tinge. Impure forms are reactive. Rusts like iron in moist air. Manganese is most abundant ores are pyrolusite (MnO₂), psilomelane [(Ba,H₂O)₂Mn₅O₁₀] and rhodochrosite (MnCO₃). Pure metal produced by mixing MnO₂ with powered Al and ignited in a furnace. Used in steel, batteries and ceramics. The steel in railroad tracks can contain as much as 1.2 % manganese. It is crucial to the effectiveness of vitamin B₁.

Newton’s gravitational law    →   Newtonov zakon gravitacije

Every object in the universe attracts every other object with a force (gravitational force F_G) directed along the line through centres of the two objects that is proportional to the product of their masses and inversely proportional to the square of the distance between them.

m₁ and m₂ are masses of the two objects and r is the distance between them. G is universal constant of gravitation, which equals 6.67•10^-26 N m² kg^-2. Strictly speaking, this law applies only to objects that can be considered pointlike object. Otherwise, the force has to be found by integrating the forces between various mass elements.

It is more properly to express Newton’s gravitational law by vector equation:

in which r₁ and r₂ are position vectors of masses m₁ and m₂.

Gravitational forces act on distance. Newton’s gravitational law is derived from Kepler’s law for planetary motion, using a physical assumption considering Sun as the centre and the source of gravitational force.

Additionally, every object moves in the direction of the force acting on it, with acceleration that is inversely proportional to the mass of object. For bodies on the surface of Earth, the distance r in gravitational law formula is practically equal to the Earth radius, R_E. If the mass of the body on Earth surface is m and the mass of earth is M_E, the gravitational force acting on that body can be expressed as:

where g is gravitational acceleration which is, although dependent on geographical latitude, usually considered as constant equal to 9.81 m s^-2.

U-tube manometer    →   U-manometar

U-tube manometer contains water or mercury in a U-shaped tube, and is usually used to measure gas pressure. One end of the U tube is exposed to the unknown pressure field (P) and the other end is connected to a reference pressure source (usually atmospheric pressure) (P_ref), shown in the schematic below.

If fluid C is the atmosphere, fluid B is the liquid in the U tube (e.g. water or mercury), and fluid A is a gas, then we can assume that ρB >> ρA, ρC. The pressure contributed by the weight of gas within the U tube can therefore be neglected. The gage pressure of the gas can be approximated by,

biocapacity    →   biokapacitet

Biocapacity (or biological capacity) is the capacity of ecosystems to produce useful biological materials and to absorb carbon dioxide generated by humans, using current management schemes and extraction technologies. Useful biological materials are defined as those used by the human economy, hence what is considered useful can change from year to year. The biocapacity of an area is calculated by multiplying the actual physical area by the yield factor and the appropriate equivalence factor.

Yield factor is a factor that accounts for differences between countries in productivity of a given land type. Each country and each year has yield factors for cropland, grazing land, forest, and fisheries.

Equivalence factor is a productivity based scaling factor that converts a specific land type into a universal unit of biologically productive area, a global hectare (gha).

cellulose    →   celuloza

Cellulose, (C₆H₁₀O₅)_n, is a polysaccharide that consists of a long unbranched chain of glucose units linked by (1→4)-β-glycoside bonds. Nature uses cellulose primarily as a structural material to impart strength and rigidity to plants. Leaves, grasses, and cotton are primarily cellulose. The fibrous nature of extracted cellulose has led to its use in textile industry for the production of cotton, artificial silk, etc. Cellulose also serves as raw material for the manufacture of cellulose acetate, known commercially as acetate rayon, and cellulose nitrate, known as guncotton. Gunncotton is the major ingredient in smokeless powder, the explosive propellant used in artillery shells and in ammunition for firearms.

paper    →   papir

Paper is the thin sheet of material made of cellulose pulp, derived mainly from wood, but also from rags and certain grasses, and processed into flexible leaves or rolls. It is manufactured by bleaching raw material using the bleaching-powder, mixing it with inorganic fillers, colours and glues, and drying. Used primarily for writing, printing, drawing, wrapping, and covering walls.

dry cell    →   suhi članak

Dry cell or Leclanche cell is a primary cell having a zinc anode, a carbon (graphite) cathode surrounded by manganese dioxide, and a paste containing ammonium chloride as electrolyte. The electromotive force (emf) produced by a dry cell is 1.5 V. Dry cell is not reversible and therefore have a limited operating life. It is invented by the French engineer Georges Leclanché (1839.-1882.) in 1866.

lithosphere    →   litosfera

Lithosphere (from the Greek for rocky sphere) is rigid, rocky outer layer of the Earth, consisting of the crust and the solid outermost layer of the upper mantle. The distinguishing characteristic of the lithosphere is not its composition but its flow properties. It floats on the asthenosphere, which is the heat-softened layer of the mantle below the lithosphere.

The lithospheric is not one continuous piece but is broken into about a dozen major separate rigid blocks, or plates, which move independently relative to one another. This movement of lithospheric plates over the asthenosphere is described as plate tectonics. When an oceanic plate and a continental plate meet, the heavier oceanic plate (composed mostly of basalt, specific gravity about 3.0 or peridotite, specific gravity about 3.3) subducts under the lighter continental plate (composed mostly of granite, specific gravity about 2.7).

absolute volume    →   apsolutni volumen

Absolute volume is the total volume of the particles in a granular material, including both permeable and impermeable voids but excluding spaces between particles.