CHEMISTRY GLOSSARY

Biot-Savart law    →   Biot-Savartov zakon

The magnetic field B due to a current-carrying conductor can be determined by Biot-Savart law. The contribution to magnetic field set up at distance r by the current element IdL is given by expression:

where μ₀ is permeability constant. It plays a role in magnetic problems equivalent to the role of permittivity constant μ₀ in electrostatics problems. In order to obtain B, contributions of all current elements have to be integrated. In case of a long straight conductor, carrying current I, Biot-Savart law gives:

SI unit for magnetic field B is tesla (T).

Permaeability constant μ₀ has value 4π×10^-7 T m A^-1.

Bohr magneton    →   Bohrov magneton

Bohr magneton (μ_B) is the atomic unit of magnetic moment, defined as

where h is Planck’s constant, m_e the electron mass, and e the elementary charge. It is the moment associated with a single electron spin.

boron    →   bor

Boron compounds have been known for thousands of years, but the element was not discovered until 1808 by Sir Humphry Davy (England) and independently by Joseph-Louis Gay-Lussac (France) and L. J. Thenard (France). The origin of the name comes from the Arabic word buraq and the Persian word burah meaning boraks. It is hard, brittle, lustrous black semimetal. Unreactive with oxygen, water, alkalis or acids. Combines with most metals to form borides. Boron is obtained from kernite, a kind of borax (Na₂B₄O₇·10H₂O). High purity boron is produced by electrolysis of molten potassium fluroborate and potassium chloride (KCl). Amorphous boron is used in pyrotechnic flares to provide a distinctive green color and in rockets as an igniter.

fermium    →   fermij

Fermium was discovered by Albert Ghiorso (USA) in 1953. Named in honour of Enrico Fermi. It is synthetic radioactive metal. Fermium was produced by bombarding lighter transuranium elements with still lighter particles or by neutron capture.

geochemistry    →   geokemija

Geochemistry is the scientific study of the chemical composition of the Earth. It includes the study of the abundance of the Earth’s elements and their isotopes and the distribution of the elements in environments of the Earth (lithosphere, atmosphere, biosphere, and hydrosphere).

heat of formation    →   toplina nastajanja

Heat of formation or enthalpy of is formation the heat evolved or absorbed when one mole of a compound is formed in its standard state from its constituent elements.

Born-Haber cycle    →   Born-Haberov kružni proces

Born-Haber cycle is a cycle of reactions used for calculating the lattice energies of ionic crystalline solids. For a compound MX, the lattice energy is the enthalpy of the reaction

The standard enthalpy of formation of the ionic solid is the enthalpy of the reaction

The cycle involves equating this enthalpy (which can be measured) to the sum of the enthalpies of a number of steps proceeding from the elements to the ionic solid. The steps are:

1) Atomization of the metal

2) Atomization of the nonmetal

3) Ionisation of the metal

This is obtained from the ionisation potential.

4) Ionisation of the nonmetal

This is electron affinity.

5) Formation of the ionic solids

Equation of the enthalpies gives

from which ΔH_L can be found.

brass    →   mjed

Brasses are alloys of copper and zinc (generally 5 % to 40 %). Brass has been known to man since prehistoric times, long before zinc itself was discovered. It was produced by melting copper together with calamine, a zinc ore. Its ductility reaches a maximum with about 30 % zinc and its tensile strength with 45 % although this property varies greatly with the mechanical and heat treatment of the alloy. Typical applications included gears, plumbing ware fittings, adapters, valves and screw machine products. The French horn is a valved brass wind instrument.

Brass may contain small amounts of other alloying elements, such as aluminum, lead, tin, or nickel. Lead can be added as an alloying element resulting in a brass that can be rapidly machined and produces minimal tool wear. Additions of aluminium, iron and manganese to brass improve strength, whilst silicon additions improve wear resistance. Brass containing tin (< 2 % ) is less liable to corrosion in seawater; it is sometimes called naval brass and is used in naval construction.

heterocyclic compounds    →   heterociklički spojevi

Heterocyclic compounds are cyclic compounds having as ring members atoms of at least two different elements, e.g., quinoline, 1,2-thiazole.

impure substance    →   nečista tvar

Impure substance is every substance that contains traces of other elements or compounds in itself.