CHEMISTRY GLOSSARY

allotropy    →   alotropija

Allotropy (Gr. allos, other, and tropos, manner) is the phenomenon of an element existing in two or more physical forms in the same physical state. The difference between the forms involves either crystaline structure (white, red and black phosphorus), the number of atoms in the molecule of a gas (diatomic oxygen and triatomic ozone), or the molecular structure of a liquid (liquid helium an helium II).

In some cases, the allotropes are stable over a temperature range, with a definite transition point at which one changes into the other. For instance, tin has two allotropes: white (metallic) tin stable above 13.2 °C and grey (nonmetallic) tin stable below 13.2 °C. This form allotropy is called enantiotropy. Form of allotropy, in which there is no transition temperature at which the two are in equilibrium, is called monotropy.

Allotropy does not apply to the substance existing in different physical states as, for example, when ice melts and changes from solid ice to liquid water.

Allotropy is generally restricted to describing polymorphic behaviour in elements, while polymorphism may refer to any material having multiple crystal structures.

alpha particle    →   alfa-čestica

Alpha particle is a helium nucleus emitted spontaneously from radioactive elements, both natural and manufactured. Its energy is in range 4-8 MeV and is dissipated in a very short path, i.e. a few centimetres of air or less than 0.005 mm of aluminium. As helium nucleus consists of two protons and two neutrons bound together as a stable entity the loss of an alpha particle involves a decrease in nucleon number of 4 and decrease of 2 in the atomic number, e.g.

A stream of alpha particles is known as an alpha ray or alpha-radiation.

chemical symbols    →   kemijski simboli

Chemical symbols are a derived way of showing elements in a formula or equation. Each symbol represents one atom and it usually consists of the first two letters of the Greek or Latin name of the element.

congener    →   srodnost

Congener is a term in chemistry that refers to one of many variants or configurations of a common chemical structure. Elements belonging to the same group on the periodic table. For example, sodium and potassium are congeners.

aluminium    →   aluminij

Aluminium was discovered by Friedrich Wöhler (Germany) in 1827. The origin of the name comes from the Latin word alumen meaning alum. It is soft, lightweight, silvery-white metal. Exposed surfaces quickly form protective oxide coating. Metal reacts violently with oxidants. Third most abundant element in the earth’s crust. Aluminium is the most abundant metal to be found in the earth’s crust, but is never found free in nature. Aluminium is obtained by electrolysis from bauxite. Used for many purposes from airplanes to beverage cans. Too soft in its pure form so less than 1 % of silicon or iron is added, which hardens and strengthens it.

argon    →   argon

Argon was discovered by Lord Raleigh and Sir William Ramsay (Scotland) in 1894. The origin of the name comes from the Greek word argos meaning inactive. It is colourless and odourless noble gas. Chemically inert. It is the third most abundant element in the earth’s atmosphere and makes up about 1 %. Argon is continuously released into the air by decay of radioactive potassium-40. Pure form is obtained from fractional distillation of liquid air. Used in lighting products. It is often used in filling incandescent light bulbs. Some is mixed with krypton in fluorescent lamps. Crystals in the semiconductor industry are grown in argon atmospheres.

Arrhenius equation    →   Arheniusova jednadžba

In 1889, Svante Arrhenius explained the variation of rate constants with temperature for several elementary reactions using the relationship

where the rate constant k is the total frequency of collisions between reaction molecules A times the fraction of collisions exp(-E_a/RT) that have an energy that exceeds a threshold activation energy E_a at a temperature of T (in kelvin). R is the universal gas constant.

astatine    →   astat

Astatine was discovered by Emilio Gino Segrè, Dale R. Corson and K. R. MacKenzie (USA) in 1940. The origin of the name comes from the Greek word astatos meaning unstable. It is unstable, radioactive member of the halogen group. Astatine does not occur in nature. Similar to iodine. Produced by bombarding bismuth with alpha particles. Since its isotopes have such short half-lives there are no commercially significant compounds of astatine.

atom    →   atom

Atom is an atom is the smallest particle of an element that retains the chemical properties of the element. Rutherford-Bohr’s model represents the atom as a positively charged core of a size around 10^-14 m composed of protons (positive particles) and neutrons (neutral particles) around which negatively charged electrons circle. The number of protons and electrons are equal, so the atom is an electrically a neutral particle. Diameter of the atom is about 10^-10 m.

Faraday constant    →   Faradayeva konstanta

Faraday constant (F) is the electric charge of 1 mol of singly charged positive ions.

where N_A is Avogadro’s constant (6.022×10²³ mol^-1) and e is the elementary charge (1.602×10^-19 C).