CHEMISTRY GLOSSARY

dye    →   bojilo

Dyes are substances used to impart colour to textiles, leather, paper, etc. Compounds used for dyeing are generally organic compounds containing conjugated double bonds. In practice dyes are classified according to the way in which the dye is applied or is held on the substrate.

chromatography    →   kromatografija

Chromatography is a method of separation of the components of a sample in which the components are distributed between two phases, one of which is stationary while the other moves. In gas chromatography, the gas moves over a liquid or solid stationary phase. In liquid chromatography, the liquid mixture moves through another liquid, a solid, or a gel. The mechanism of separation of components may be adsorption, differential solubility, ion-exchange, permeation, or other mechanisms.

clay triangle    →   trokut za žarenje

Clay triangle is a piece of laboratory equipment used in the process of heating substances by a Bunsen burner (e.g. to support a crucible when it’s being heated).

convection    →   konvekcija

Convection is the process by which heat is transferred from one part of a fluid to another by movement of the fluid itself. There are two methods by which this can be carried out.

Natural convection, in which movement occurs as a result of gravity. Heat transferred through a fluid medium, such as air or water, by currents that result from the rising of less dense, warm fluid and the sinking of heavier, cooler fluid.

Forced convection is where hot fluid is transferred from one region to another by a mechanical means (fans or pumps).

dioxin    →   dioksin

Dioxin is a general term that describes a group of hundreds of chemicals that are highly persistent in the environment. The most toxic compound is 2,3,7,8-tetrachlorodibenzo-p-dioxin or TCDD. The toxicity of other dioxins and chemicals like PCBs that act like dioxin are measured in relation to TCDD. Dioxin is formed as an unintentional by-product of many industrial processes involving chlorine such as waste incineration, chemical and pesticide manufacturing and pulp and paper bleaching. Dioxin was the primary toxic component of Agent Orange, found at Love Canal in Niagara Falls, NY and was the basis for evacuations at Times Beach, MO and Seveso, Italy.

Dioxin is formed by burning chlorine-based chemical compounds with hydrocarbons. The major source of dioxin in the environment comes from waste-burning incinerators of various sorts and also from backyard burn-barrels. Dioxin pollution is also affiliated with paper mills which use chlorine bleaching in their process, with the production of Polyvinyl Chloride (PVC) plastics, and with the production of certain chlorinated chemicals (like many pesticides).

filter    →   filtar

Filter is a device for separating solid particles from a liquid or a gas. The simplest laboratory filter for liquids is a funnel in which a cone of paper (filter paper) is placed. Special containers with a porous base of sintered glass are also used.

Einstein, Albert    →   Einstein, Albert

Albert Einstein (1879-1955) is a German born American physicist, who took Swiss nationality in 1901. A year later he went to work in the Bern patent office. In 1905. he published five enormously influential papers, one on Brownian movement, one on the photoelectric effect, one on the special theory of relativity, and one on energy and inertia (which included the famous expression E = mc²). In 1915 he published the general theory of relativity, concerned mainly with gravitation. In 1921 he was awarded the Nobel Prize. In 1933, as a Jew, Einstein decided to remain in the USA (where he was lecturing), as Hitler had come to power. For the remainder of his life he sought a unified field theory. In 1939 he informed president Roosevelt that an atom bomb was feasible and that. Germany might be able to make one.

electrode potential    →   elektrodni potencijal

Electrode potential is defined as the potential of a cell consisting of the electrode in question acting as a cathode and the standard hydrogen electrode acting as an anode. Reduction always takes place at the cathode, and oxidation at the anode. According to the IUPAC convention, the term electrode potential is reserved exclusively to describe half-reactions written as reductions. The sign of the half-cell in question determines the sign of an electrode potential when it is coupled to a standard hydrogen electrode.

Electrode potential is defined by measuring the potential relative to a standard hydrogen half cell

The convention is to designate the cell so that the oxidised form is written first. For example

The e.m.f. of this cell is

By convention, at p(H₂) = 101325 Pa and a(H⁺) = 1.00, the potential of the standard hydrogen electrode is 0.000 V at all temperatures. As a consequence of this definition, any potential developed in a galvanic cell consisting of a standard hydrogen electrode and some other electrode is attributed entirely to the other electrode

forging    →   kovanje

To forge means to displace metal under compression by a locally applied force, usually at hot working temperatures, which changes some mechanical properties of the metal.

manganometry    →   manganometrija

Manganometry is a quantitative oxidimetric method based on measurement of potassium permanganate (KMnO₄) spent for an oxidation of the matter in question.