CHEMISTRY GLOSSARY

complete ionic equation    →   potpuna ionska jednadžba

Complete ionic equation is a balanced equation that describes a reaction occurring in a solution, in which all strong electrolytes are written as dissociated ions.

cathode    →   katoda

Cathode is a negative electrode of an electrolytic cell to which positively charged ions (cations) migrate when a current is passed as in electroplating baths.

In a primary or secondary cell (battery or accumulator) the cathode is the electrode that spontaneously becomes negative during discharge, and form which therefore electrons emerge.

In vacuum electronic devices electrons are emitted by the cathode and flow to the anode.

corrosion    →   korozija

Corrosion is a harmful and undesirable construction material consumption by the chemical activity of its surroundings. Corrosion concept refers to metal and nonmetal construction materials, but it is usually used for metals, Corrosion of metal, according to the mechanism process, is divided into chemical (corrosion in nonelectrolytes) and electrochemical (corrosion in electrolytes).

Chemical corrosion appears by direct action of molecule of some element or compound on metal, thus directly creating corrosion products.

Electrochemical corrosion of metals occurs in electrolytes, so reduction of metal atom into free cation appears which by secondary processes gives molecules of compound which are considered a corrosion product.

diffusion current    →   difuzijska struja

Diffusion current (i_d) is a current which is limited by the speed of particle diffusion in an electrolyte solution.

dissociation    →   disocijacija

Dissociation is the process by which a chemical combination breaks up into simpler constituents as a result of either added energy (dissociated by heat), or the effect of a solvent on a dissolved polar compound (electrolytic dissociation). It may occur in the gaseous, solid, or liquid state, or in a solution.

An example of dissociation is the reversible reaction of hydrogen iodide at high temperatures

The term dissociation is also applied to ionisation reactions of acids and bases in water. For example

which is often regarded as a straightforward dissociation into ions

electroanalytical chemistry    →   elektroanalitička kemija

Electroanalytical chemistry chemistry is the application of electrochemical cells and electrochemical techniques for chemical analysis. The analyte is dissolved in the electrolyte of the cell, and one can perform either qualitative analysis (determination of the type of constituents present) or quantitative analysis (determination of the amount of a given constituent).

electrode    →   elektroda

Electrode is a conductor that emits or collects electrons in a electrolytic cell

electromotive force    →   elektromotorna sila

Electromotive force (e.m.f. or E_MF) is the difference in electric potential that exists between two dissimilar electrodes immersed in the same electrolyte or otherwise connected by ionic conductors.

electroorganic reaction    →   elektroorganske reakcije

Electroorganic reaction is an organic reaction produced in an electrolytic cell. Electroorganic reactions are used to synthesise compounds that are difficult to produce by conventional techniques. An example of an electroorganic reaction is Kolbe’s method of synthesising alkanes.

dry cell    →   suhi članak

Dry cell or Leclanche cell is a primary cell having a zinc anode, a carbon (graphite) cathode surrounded by manganese dioxide, and a paste containing ammonium chloride as electrolyte. The electromotive force (emf) produced by a dry cell is 1.5 V. Dry cell is not reversible and therefore have a limited operating life. It is invented by the French engineer Georges Leclanché (1839.-1882.) in 1866.