Faraday’s laws of electrolysis are two laws found by British chemist and physicist Michael Faraday (1791-1867) in his experiments on electrolysis:
1. The quantity of matter extracted on the electrode is proportional to the quantity of charge (Q = I·t) which has flown in electrolysis time.
where z = number of electrons changed in reaction and F = Faraday’s constant which equals 96 487 C mol-1.
2. The masses of the elements liberated by the same quantity of electricity are directly proportional to their chemical equivalents.
96 487 C will discharge 1 mol Ag and 1/2 mol Cu. The relevant half reactions are:
Gauss’ law describes the relation between charge and electric field in static situations, so it is equivalent to Coulomb’s law, which can be derived from Gauss’ law. Gauss’ law states that the net flux of electric field, Φ, through an imaginary closed surface, S, - a Gaussian surface - is equal to the net charge, q, inside that closed surface:
where electric flux Φ through Gaussian surface is given by:
ε0 is the permittivity constant and dS is a surface element.
Volumetry consists of adding an equivalent amount of a reagent of exactly known concentration to the analyte. From stechiometrical proportion and added volume of reagent the quantity of matter in question can be calculated.
Hydrosphere (from the Greek for water sphere) is a discontinuous layer of water on, under, and over the Earth's surface. It includes all liquid and frozen surface waters, groundwater held in soil and rock, and atmospheric water vapour. Water continuously circulates between these reservoirs in what is called the hydrologic cycle, which is driven by energy from the Sun.
Reservoir | V / 106 km3 | w / % |
---|---|---|
oceans | 1 370.0 | 97.25 |
ice caps and glaciers | 29.0 | 2.05 |
groundwater | 9.5 | 0.68 |
lakes, rivers | 0.127 | 0.01 |
soil moisture | 0.065 | 0.005 |
atmosphere (as liquid equivalent of water vapour) | 0.013 | 0.001 |
biosphere | 0.0006 | 0.00004 |
TOTAL | 1 408.7 | 100 |
Ion-exchanger is a solid or liquid material containing ions that are exchangeable with other ions with a like charge that are present in a solution in which the material is insoluble. Ion-exchange resins consist of various copolymers having a cross-linked three-dimensional structure to which ionic groups have been attached.
Mass (m) is the quantity of matter contained in a particle or body regardless of its location in the universe. Mass is constant, whereas weight is affected by the distance of a body from the centre of the Earth (or of other planet). The SI unit is kilogram.
According to the Einstein equation
all forms of energy possess a mass equivalent.
Generalic, Eni. "Ekvivalent." Croatian-English Chemistry Dictionary & Glossary. 29 June 2022. KTF-Split. {Date of access}. <https://glossary.periodni.com>.
Glossary
Periodic Table