CHEMISTRY GLOSSARY

hydrolysis    →   hidroliza

Hydrolysis is a chemical reaction in which water reacts with another substance to form two or more new substances. This involves ionisation of the water molecule, as well as splitting of the compound hydrolysed, e.g.

Examples are conversion of starch to glucose by water in the presence of suitable catalysts and a reaction of the ions of a dissolved salt to form various products, such as acids, complex ions, etc.

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hydrophobic interaction    →   hidrofobne interakcije

Hydrophobic interaction is the tendency of hydrocarbons (or of lipophilic hydrocarbon-like groups in solutes) to form intermolecular aggregates in an aqueous medium, and analogous intramolecular interactions. The name arises from the attribution of the phenomenon to the apparent repulsion between water and hydrocarbons. Use of the misleading alternative term hydrophobic bond is discouraged.

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hydrosphere    →   hidrosfera

Hydrosphere (from the Greek for water sphere) is a discontinuous layer of water on, under, and over the Earth's surface. It includes all liquid and frozen surface waters, groundwater held in soil and rock, and atmospheric water vapour. Water continuously circulates between these reservoirs in what is called the hydrologic cycle, which is driven by energy from the Sun.

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indium    →   indij

Indium was discovered by Ferdinand Reich and Hieronymus Theodor Richter (Germany) in 1863. Named after the indicum (colour indigo), the colour it shows in a spectroscope. It is rare, very soft, silver-white metal. Stable in air and water. Dissolves in acids. Metal can ignite and burn. Indium is found in certain zinc ores. Used to coat high speed bearings and as an alloy that lowers the melting point of other metals. Relatively small amounts are used in dental items and in electronic semiconductors.

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invert sugar    →   invertni šećer

Invert sugar is a mixture of equal parts of glucose and fructose resulting from the hydrolysis of sucrose (saccharose). The name stemming from the fact that it rotates of plane polarized light in the opposite direction of sucrose. Sucrose is dextrorotatory - it rotates polarized light clockwise ([α]_D = +66.5°). Invert sugar rotates the plane of the polarized light counterclockwise ([α]_D = -22°) due to the strongly levorotatory nature of fructose ([α]_D = -92°).

Homemade artificial honey (invert sugar syrup): Dissolve two parts of household sugar (1 kg) with stirring in one part of water (0.5 kg) in a saucepan over low heat. Add 1 g of citric acid or the juice of one lemon to the mixture. Bring the ingredients to a slow boil. It can take anywhere between 15 minutes to 1 hour. The end result is sticky, golden syrup. Let it sit at room temperature until it is cool.

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iodine    →   jod

Iodine was discovered by Bernard Courtois (France) in 1811. The origin of the name comes from the Greek word iodes meaning violet. It is shiny, black, non-metallic solid with characteristic odour. Sublimes easily and as a gas it is violet and intensely irritating to the eyes, nose and throat. Iodine occurs on land and in the sea in sodium and potassium compounds. Required in small amounts by humans. Once used as an antiseptic, but no longer due to its poisonous nature.

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ion exchanger    →   ionski izmjenjivač

Ion-exchanger is a solid or liquid material containing ions that are exchangeable with other ions with a like charge that are present in a solution in which the material is insoluble. Ion-exchange resins consist of various copolymers having a cross-linked three-dimensional structure to which ionic groups have been attached.

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ionisation    →   ionizacija

Ionisation is the process of producing ions. Certain molecules ionise in a solution; for example, acids ionise when dissolved in water.

Electron transfer also causes ionisation in certain reactions, for example sodium and chlorine react by transfer of a valence electron from the sodium atom to the chlorine atom to form the ions that constitute a sodium chloride crystal.

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iridium    →   iridij

Iridium was discovered by Smithson Tennant (England) in 1803. The origin of the name comes from the Latin word iris, meaning rainbow, because its salts are highly colored. It is heavy, brittle, white metal. Unreactive in air, water and acids. Attacked by fused NaOH. Metal ignites and burns readily. Iridium is found in gravel deposits with platinum. Used with osmium to tip gold pen points, to make crucible and special containers. Also to make alloys used for standard weights and measures and heat-resistant alloys. Also as hardening agent for platinum.

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kelvin    →   kelvin

Kelvin (K) is the SI base unit of thermodynamic temperature.

The kelvin, unit of thermodynamic temperature, is the fraction 1/273.16 of the thermodynamic temperature of the triple point of water. The unit was named after the British scientist Sir. W. Thompson, Lord Kelvin (1824-1907).

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