CHEMISTRY GLOSSARY

trigonal pyramidal molecular geometry    →   trigonska piramidalna geometrija molekule

Trigonal pyramidal is a molecular shape that results when there are three bonds and one lone pair on the central atom in the molecule. Molecules with an tetrahedral electron pair geometries have sp³ hybridization at the central atom. Ammonia (NH₃) is a trigonal pyramidal molecule.

triple bond    →   trostruka veza

Triple bond. (≡) is a covalent bond that involves 3 bonding pairs. In the valence bond theory, one of the bonds in a triple bond is a sigma bond and the other two are pi bonds. For example, the central bond in acetylene is a triple bond: H-C≡C-H.

triple point    →   trojna točka

Triple point is the point in p,T space where the solid, liquid, and gas phases of a substance are in thermodynamic equilibrium.

troposphere    →   troposfera

Troposphere is the lowest part of the earth’s atmosphere, extending to 10 km to 15 km above the surface. It is characterized by a decrease in temperature with increasing altitude. The exact height varies with latitude and season.

tryglyceride    →   triglicerid

Triglyceride is an ester of glycerol and three fatty acids. It is the main constituent of vegetable oil and animal fats. The fatty acids attached to the glycerol can be the same or different. Natural fatty acids found in plants and animals are typically composed only of even numbers of carbon atoms (usually from 16 to 20) due to the way they are bio-synthesized from acetyl CoA.

tryptophan    →   triptofan

Tryptophan is hydrophobic amino acids with aromatic side chain. Tryptophan is large aromatic residue that is normally found buried in the interior of a protein and is important for protein stability. Tryptophan has the largest side chain and is the least common amino acid in proteins. It has spectral properties that make it the best inherent probe for following protein folding and conformational changes associated with biochemical processes. It is an essential amino acid, which means that humans cannot synthesize it, so it must be ingested.

• Abbreviations: Trp, W
• IUPAC name: 2-amino-3-(1H-indol-3-yl)propanoic acid
• Molecular formula: C₁₁H₁₂N₂O₂
• Molecular weight: 204.23 g/mol

tyrosine    →   tirozin

Tyrosine is hydrophobic amino acids with aromatic side chain. Tyrosine is large aromatic residue that is normally found buried in the interior of a protein and is important for protein stability. Tyrosine has special properties since its hydroxyl side chain may function as a powerful nucleophile in an enzyme active site (when ionized) and is a common site for phosphorylation in cell signaling cascades. Tyrosine absorbs ultraviolet radiation and contributes to the absorbance spectra of proteins. It is not essential (or semi-essential) to the human diet, since it is synthesized in the body from other metabolites.

• Abbreviations: Tyr, Y
• IUPAC name: 2-amino-3-(4-hydroxyphenyl)propanoic acid
• Molecular formula: C₉H₁₁NO₃
• Molecular weight: 181.19 g/mol

U-tube    →   U-cijev

U-tube filled with a sodium hydroxide is used for a cleaned and dried gas.

U-tube filled with a 1 mol dm^-3 aqueous potassium nitrate solution is used as a permanent salt bridge.

U-tube is a device used for water electrolysis, for laboratory hydrogen and oxygen obtaining.

U-tube manometer    →   U-manometar

U-tube manometer contains water or mercury in a U-shaped tube, and is usually used to measure gas pressure. One end of the U tube is exposed to the unknown pressure field (P) and the other end is connected to a reference pressure source (usually atmospheric pressure) (P_ref), shown in the schematic below.

If fluid C is the atmosphere, fluid B is the liquid in the U tube (e.g. water or mercury), and fluid A is a gas, then we can assume that ρB >> ρA, ρC. The pressure contributed by the weight of gas within the U tube can therefore be neglected. The gage pressure of the gas can be approximated by,

ultraviolet light    →   ultraljubičasto svjetlo

Ultraviolet light (UV light or UV radiation) is an electromagnetic radiation with a wavelength longer than that of x-rays, but shorter than that of visible light. Ultraviolet light can break some chemical bonds and cause cell damage.