CHEMISTRY GLOSSARY

acceleration    →   akceleracija

If a point-like object undergoes a change in velocity Δv=v_f-v_i in time Δt=t_f-t_i (indexes i and f stand for initial and final instant as well as for initial and final velocity) its average acceleration, a is defined as

The instantaneous acceleration, a, is obtained from the average acceleration by shrinking the time interval Δt towards zero. The average acceleration approaches a limiting value, which is the acceleration of a given instant:

Acceleration is a vector quantity. SI unit for acceleration is m s^-2.

agar    →   agar

Agar, also called agar-agar, is an extract of certain species of red algae (of the Gelidium and Gracilaria genera) that is used as a gelling agent in microbiological culture media, foodstuffs, medicine, and cosmetic. The predominant component of agar is agarose, a polysaccharide made up of subunits of the sugar galactose.

agarose    →   agaroza

Agarose is a polysaccharide obtained from agar that is used for a variety of life science applications especially in gel electrophoresis. The structure of agarose consists of alternating (1→3)-linked β-D-galactopyranose and (1→4)-linked 3,6-anhydro-α-L-galactopyranose.

AMU    →   AMU

AMU or atomic mass unit is a unit of mass used to express relative atomic masses. It is equal to 1/12 of the mass of an atom of the isotope carbon-12 and is equal to 1.66 033×10^-27 kg. This unit superseded both the physical and a chemical mass unit based on oxygen-16 and is sometimes called the unified mass unit or the dalton.

angstrom    →   angstrem

Ångström (Å) is a unit of length equal to 10^-10 m. The Ångström is defined in terms of the wavelength of the emission spectra’s red line of an atom of cadmium (6438.4696 Å).

activity    →   aktivitet

Activity (a) is a thermodynamic function used in place of concentration in equilibrium constants for reactions involving nonideal gases and solutions. For the species i activity is defined as

where a_i is the activity of the species i, c_i is its molar concentration, and f_i is a dimensionless quantity called the activity coefficient.

activity coefficient    →   koeficijent aktiviteta

Activity coefficient (γ or f) is a fractional number which, when multiplied by the molar concentration of a substance in solution, yields the chemical activity. This term gives an idea of how much interaction exists between molecules at higher concentration.

In solutions of very low ionic strength, when m is less than 0.01, the Debye-Hückel limiting law can be used to calculate approximate activity coefficients

where γ_i = activity coefficient of the species i, z_i = charge on the species i and μ = ionic strength of the solution.

alpha particle    →   alfa-čestica

Alpha particle is a helium nucleus emitted spontaneously from radioactive elements, both natural and manufactured. Its energy is in range 4-8 MeV and is dissipated in a very short path, i.e. a few centimetres of air or less than 0.005 mm of aluminium. As helium nucleus consists of two protons and two neutrons bound together as a stable entity the loss of an alpha particle involves a decrease in nucleon number of 4 and decrease of 2 in the atomic number, e.g.

A stream of alpha particles is known as an alpha ray or alpha-radiation.

are    →   ar

Are (a) is a unit of area equal to 100 m². The unit is still used in agriculture.

atmospheric pressure    →   atmosferski tlak

Atmospheric pressure is the pressure exerted by weight of the air above it at any point on the earth’s surface. At sea level the atmosphere will support a column of mercury about 760 mm high. This decreases with increasing altitude. The standard value for the atmospheric pressure at sea level in SI units is 101 325 Pa.