CHEMISTRY GLOSSARY

acid-base titration    →   kiselo-bazna titracija

Acid-base titration is an analytical technique in volumetric analysis, where an acid of known concentration is used to neutralise a known volume of a base, and the observed volume of the acid required is used to determine the unknown concentration of the base. An acid-base indicator is used to determine the end-point of the titration.

aliquot    →   alikvot

Aliquot is a known volume of liquid that represents a part of some larger volume. It is usually taken with a pipette from a measured flask.

aqua regia    →   zlatotopka

Aqua regia is a mixture of one volume part of nitric acid (HNO₃) and three volume parts of hydrochloric acid (HCl). Dissolving of gold in aqua regia is described by the following equation:

atom radius    →   radijus atoma

Atoms and molecules have no strict boundaries. The volume of a free atom is usually defined as that volume that contains 90 % of electron cloud. The radius of an atom represents half of interatom distance of two identical atoms which are in touch but are not interconnected either by a covalent or an ionic bond, but with a very weak van der Waals’s bond.

Avogadro, Amadeo    →   Avogadro, Amadeo

Amadeo Avogadro (1776-1856) is an Italian chemist and physicist that proposed a correct molecular explanation for Gay-Lussac’s law of combining volumes. His work provided a simple way to determine atomic weights and molecular weights of gases. He is published a theory about the movement of particles in gases that became known as Avogadro’s Law.

Avogadro’s law    →   Avogadrov zakon

Avogadro’s law: Equal volumes of all gases contain equal numbers of molecules at the same pressure and temperature. The law, often called Avogadro’s hypothesis, is true only for ideal gases. It was proposed in 1811 by Italian chemist Amadeo Avogadro (1776-1856).

chlorosity    →   klorocitet

Chlorosity is the quantity determined by volumetric methods and is defined in the same manner as chlorinity except that the sample unit is 1 L of sea water rather than 1 kg of sea water weighed in vacuo.

conductometry    →   konduktometrija

Conductometry is a volumetric analytic method in which the end of titration (equivalent point) is defined by an electric conductivity appliance.

equation of state    →   jednadžba stanja

Equation of state is an equation relating the pressure, volume, and temperature of a substance or system. Equation of state for ideal gas

where p is pressure, V molar volume, T temperature, and R the molar gas constant (8.314 JK^-1mol^-1).

body-centered cubic lattice    →   prostorno centrirana kubična rešetka

Body-centered cubic lattice (bcc or cubic-I), like all lattices, has lattice points at the eight corners of the unit cell plus an additional points at the center of the cell. It has unit cell vectors a = b = c and interaxial angles α=β=γ=90°.

The simplest crystal structures are those in which there is only a single atom at each lattice point. In the bcc structures the spheres fill 68 % of the volume. The number of atoms in a unit cell is two (8 × 1/8 + 1 = 2). There are 23 metals that have the bcc lattice.