CHEMISTRY GLOSSARY

dropping mercury electrode    →   kapajuća živina elektroda

Dropping mercury electrode (DME) is a working electrode arrangement for polarography in which mercury continuously drops from a reservoir through a capillary tube (internal diameter 0.03 - 0.05 mm) into the solution. The optimum interval between drops for most analyses is between 2 and 5 s. The unique advantage to the use of the DME is that the constant renewal of the electrode surface, exposed to the test solution, eliminates the effects of electrode poisoning.

sample    →   uzorak

In chemical analysis total amount of matter is not analysed, but only a smaller part of it. This small part is called analysis sample and it must represent the whole amount of the matter that is being analysed.

smog    →   smog

Smog is a mixture of smoke and fog. The term is used to describe city fogs in which there is a large proportion of particulate matter (tiny pieces of carbon from exhausts) and also a high concentration of sulphur and nitrogen gases.

stp    →   stp

STP (or NTP) is abbreviation for standard (normal) temperature (273.15 K or 0 °C) and pressure (10⁵ Pa). These conditions are used when comparing the properties of gases.

electric field    →   električno polje

If a small amount of charge experience a force, there is an electric field in the vicinity. Electric field E is defined in terms of electrostatic force F that would be exerted on positive test charge q_p placed in the field:

SI unit for electric field is N C^-1, or V m^-1.

The electric field due to a point charge q at distance r from it given by:

where ε₀ is permittivity constant, and is ε_o=8.85×10^-12 C² N^-1 m^-2.

electrodeposition    →   elektrodepozicija

Electrodeposition is a process of depositing solid materials on an electrode surface using electrolysis. It is a somewhat loosely used term that is applied to many technologies. There are a number of metal deposition technologies. However, not only metals but also different compounds can be electrodeposited. This is used most often for the formation of oxides (such as manganese dioxide and lead dioxide) by anodic oxidation of dissolved salts.

electroplating    →   galvaniziranje

Electroplating (also called electrodeposition) is the deposition of a metallic coating onto an object by putting a negative charge onto the object and immersing it into a solution which contains a salt of the metal to be deposited. The metallic ions of the salt carry a positive charge and are attracted to the part. When they reach it, the negatively charged part provides the electrons to reduce the positively charged ions to metallic form.

Typically, a brass or nickel object is coated with a layer of silver by making use of electrolysis of a silver solution, using the object to be coated as the cathode. The anode consist of pure silver, and the cathode is the object to be plated. The electrolyte is a mixure of silver nitrate with potassium cyanide. The reactions are:

The cyanide ensures a low concentration of silver ions, a condition for providing the best plating results.

thermochemistry    →   termokemija

Termochemistry is the study of heat absorbed or released during chemical changes.

toxicant    →   toksikant

Toxicant is a comparatively rarely-used term which describes any material which is potentially toxic.

toxicity    →   toksičnost

The term toxicity is very widely used in the safety context. It is used in two contrasting senses: to denote the capacity to cause harm to a living organism, and to indicate the adverse effects caused by a chemical.