CHEMISTRY GLOSSARY

allotrope    →   alotrop

Allotropes are the elements which exist in two or more different forms in the same physical state. Allotropes generally differ in physical properties and may also differ in chemical activity.

Diamond, graphite and fullerenes are three allotropes of the element carbon. Graphite is a soft, black, slippery substance; by contrast, diamond is one of the hardest substances known. The different properties of the allotropes arise from their chemical structures. Diamonds typically crystallize in the cubic crystal system and consist of tetrahedrally bonded carbon atoms. Graphite crystallizes in the hexagonal system. In the fullerenes, the carbon atoms taking the form of a hollow sphere, ellipsoid, or tube.

In some cases, the allotropes are stable over a temperature range, with a definite transition point at which one changes into the other. For instance, tin has two allotropes: white (metallic) tin stable above 13.2 °C and grey (nonmetallic) tin stable below 13.2 °C.

The term allotropes may also be used to refer to the molecular forms of an element. Ozone is a chemically active triatomic allotrope of the element oxygen.

Dalton, John    →   Dalton, John

Dalton, John (1766-1844) British chemist and physicist. In 1801 he formulated his law of partial pressures (Dalton’s law), but he is best remembered for Dalton’s atomic theory, which he announced in 1803. Dalton also studied colour blindness (a condition, once called Daltonism, that he shared with his brother).

diazo compounds    →   diazo-spojevi

Diazo compounds are compounds having the divalent diazo group, =N⁺=N^-, attached to a carbon atom. The term includes azo compounds, diazonium compounds, and also such compounds as diazomethane, CH₂=N₂.

alpaca    →   alpaka

Alpaca (alpaka) or Nickel Silver is the generic name for any of a range of non-precious bright silvery-grey metal alloys, composed of copper, nickel and zinc. Despite its name it contains no real silver. It is also commonly called German Silver.

There are many different formulations of alloys which fall within the general term of Nickel Silver. All contain copper, nickel and zinc, while some formulations may additionally include antimony, tin, lead or cadmium. A representative formulation is 65 % copper, 18 % nickel, 17 % zinc. Nickel Silver is widely used for the commercial production of industrial components, housewares, flatware and cutlery, and as the metal substrate for silver-plated goods.

aromatic compounds    →   aromatski ugljikovodici

Aromatic compounds are a major group of unsaturated cyclic hydrocarbons containing one or more rings, typified by benzene, which has a 6-carbon ring containing three double bonds. All the bonds in benzene (C₆H₆) are the same length intermediate between double and single C-C bonds. The properties arise because the electrons in the p-orbitals are delocalised over the ring, giving extra stabilization energy of 150 kJ/mol over the energy of Kekulé structure. Aromatic compounds are unsaturated compounds, yet they do not easily partake in addition reactions.

Historical use of the term implies a ring containing only carbon (e.g., benzene, naphthalene), but it is often generalized to include heterocyclic structures such as pyridine and thiophene.

battery    →   baterija

Battery a device that converts chemical energy to electrical energy. The process underlying the operation of a battery involves a chemical reaction in which electrons are transferred from one chemical species to another. This process is carried out in two half-reactions, one that involves the loss of electrons and one that involves their gain. The battery is an electrochemical cell divided in two half-cells, and reaction proceeds when these are connected together by an electrically conducting pathway. The passage of electrons from one half-cell to the other corresponds to an electric current. Each half-cell contains an electrode in contact with the reacting species. The electrode which passes electrons into the circuit when battery discharges is called anode and is negative terminal. The electrode which receives electrons is called cathode, and is the battery’s positive terminal. The electrical circuit is completed by an electrolyte, an electrically conducting substance placed between the two electrodes which carriers a flow of charge between them. In wet cells, the electrolyte is a liquid containing dissolved ions, whose motion generates an electrical current; in dry cells the electrolyte is basely solid, for example, a solid with mobile ions or porous solid saturated with an ionic solution.

dienes    →   dieni

Dienes are unsaturated organic compounds that contain two fixed double bonds between carbon atoms. Dienes in which the two double-bond units are linked by one single bond are termed conjugated.

dolomite    →   dolomit

Dolomite is a carbonate mineral consisting of a mixed calcium-magnesium carbonate, CaCO₃·MgCO₃, crystallising in the rhombohedral system. It is usually white or colourless. The term is also used to denote a rock with a high ratio of magnesium to calcium carbonate.

drug    →   droga

Drug as a term is used for compounds that can cause addiction with an emphasis on narcotics. It is a biologically active compound or mixture used to cure, prevent, or detect disease, to control biological processes, or to alter the mental state.

effusion    →   efuzija

Effusion is the flow of a gas through a small aperture. The relative rates at which gases effuse, under the same conditions, is approximately inversely proportional to the square of their densities.