CHEMISTRY GLOSSARY

normal conditions    →   normalni uvjeti

Gas is under normal (or standard) conditions when: p₀ = 10⁵ Pa and T₀ = 273.15 K (0 °C). IUPAC recommends that the former use of the pressure of 1 atm as standard pressure (equivalent to 101 325 Pa) should be discontinued. At these conditions, the molar volume of gas V_m0 is 0.022 711 m³ (22.711 L).

conditional electrode potential    →   uvjetni elektrodni potencijal

Conditional or formal electrode potential (E°’) is equal to electrode potential (E) when overall concentrations of oxidised and reduced form in all its forms in a solution are equal to one. Conditional electrode potential includes all effects made by reactions that do not take part in the electron exchange, but lead to change of ion power, changes of pH, hydrolysis, complexing, precipitating, etc.

At 298 K (25 °C) and by converting natural (Napierian) logarithms into decimal (common, or Briggian) logarithms, Nernst’s equation for electrode potential can be written as follows:

terminal    →   terminalni

Terminal in chemistry means: the end of a polymer molecule and a point at which electron connections can easily be made or broken.

terminal reaction    →   terminalna reakcija

Terminal reaction is a reaction that ends a cycle or chain of other chemical reactions.

termination    →   terminacija

Termination is the final step in a free radical mechanism that results in the stopping of the free radical reaction.

accelerated corrosion test    →   ubrzana korozija

Accelerated corrosion test is method designed to approximate, in a short time, the deteriorating effect under normal long-term service conditions.

covering power    →   prekrivna moć

Covering power is the ability of a plating solution under a set of specified plating conditions to deposit metal on the surfaces of recesses or deep holes. This term suggests an ability to cover, but not necessarily to build up, a uniform coating.

combustible    →   zapaljiv

The term combustible is often used to describe any material which will burn. However, conditions at which combustion will occur must be defined more accurately, for example a combustible liquid is 37.8 °C but below 93.3 °C. This allows a distinction to be made between combustible materials, which are fairly difficult to ignite, and flammable or highly flammable ones, which are far easier to ignite.

melting point    →   talište

Melting point is the temperature at which a solid becomes a liquid at normal atmospheric pressure.

A more specific definition of melting point (or freezing point) is the temperature at which the solid and liquid phases of a substance are in equilibrium at a specified pressure (normally taken to be atmospheric unless stated otherwise). A pure substance under standard condition of pressure has a single reproducible melting point. The terms melting point and freezing point are often used interchangeably, depending on whether the substance is being heated or cooled.

acetal    →   acetal

Acetals are organic compounds having the structure R₂C(OR’)₂ (R’ ≠ H). They are organic compounds formed by addition of alcohol molecules to aldehyde or ketone molecules. Originally, the term was confined to derivatives of aldehydes (one R = H), but it now applies equally to derivatives of ketones (neither R = H ). Mixed acetals have different R’ groups. The formation of acetals is reversible; acetals can be hydrolysed back to aldehydes (ketone) in acidic solutions.

Acetal, 1,1-diethoxyethane (CH₃CH(OC₂H₅)₂), is an organic compound, pleasant smelling, formed by addition of ethyl alcohol to ethanal (acetaldehyde). It is used as a solvent and in synthetic organic chemistry.