CHEMISTRY GLOSSARY

Curie    →   Curie

Maria Sklodowska-Curie (1867-1934) Polish-born French chemist who went to Paris in 1891. She married the physicist Pierre Curie (1859-1906) in 1985 and soon began work on seeking radioactive elements other than uranium in pitchblende (to account for its unexpectedly high radioactivity). By 1898 she had discovered radium and polonium although it took her years to purify them. In 1903 the Curies shared the Nobel Prize for physics with Henri Becquerel, who had discovered radioactivity.

cyclic compound    →   ciklički spoj

Cyclic describing a compound that has a ring of atoms in its molecules. In homocyclic compounds all the atoms in the ring are of the same type, e.g. benzene (C₆H₆) and cyclohexane (C₆H₁₂). These two examples are also examples of carbocyclic compounds; i.e. the rings are made of carbon atoms. If different atoms occur in the ring, as in pyridine (C₅H₅N), the compound is said to be heterocyclic.

cyclic voltammetry    →   ciklička voltametrija

Cyclic voltammetry (CV) is an electrochemical measuring technique used for the determination of the kinetics and mechanism of electrode reactions. The potential of the working electrode is controlled (typically with a potentiostat) and the current flowing through the electrode is measured. It is a linear-weep voltammetry with the scan continued in the reverse direction at the end of the first scan. This cycle can be repeated a number of times, and is used for corrosion studies.

Fermi level    →   Fermijev nivo

Fermi level is the highest energy of occupied states in a solid at zero temperature. The Fermi level in conductors lies in the conduction band, in insulators it lies in the valence band, and in semiconductors it falls in the gap between the conduction band and the valence band. It was named after the Italian physicst Enrico Fermi (1901 - 1954).

fermion    →   fermioni

Fermion is any particle with spin equal to an odd multiple of 1/2. Fermion is a particle that obeys Fermi-Dirac statistics, e.g. electron, proton, neutron, muon, etc.

fermium    →   fermij

Fermium was discovered by Albert Ghiorso (USA) in 1953. Named in honour of Enrico Fermi. It is synthetic radioactive metal. Fermium was produced by bombarding lighter transuranium elements with still lighter particles or by neutron capture.

fire-damp    →   plin praskavac

Fire-damp is a mixture of two volume parts of hydrogen and one volume part of oxygen which, if set on fire, strongly explodes, the flame giving of a very high temperature (2 000 °C).

cysteine    →   cistein

Cysteine is neutral amino acids with polar side chains. Because of its high reactivity, the thiol group of cysteine has numerous biological functions. It serves as a potent nucleophile and metal ligand (particularly for iron and zinc), but is best known for its ability to form disulfide bonds, which often make an important contribution to the stability of extracellular proteins. Cysteine is a non-essential amino acid, which means that it is biosynthesized in humans.

• Abbreviations: Cys, C
• IUPAC name: 2-amino-3-sulfanylpropanoic acid
• Molecular formula: C₃H₇NO₂S
• Molecular weight: 121.16 g/mol

Dalton’s atomic theory    →   Daltonova atomska teorija

Dalton’s atomic theory is a theory of chemical combination, first stated by John Dalton in 1803. It involves the following postulates:

1. Elements consist of indivisible small particles (atoms).

2. All atoms of the same element are identical; different elements have different types of atom.

3. Atoms can neither be created nor destroyed.

4. ’Compound elements’ (i.e. compounds) are formed when atoms of different elements join in simple ratios to form ’compound atoms’ (i.e. molecules).

Dalton also proposed symbols for atoms of different elements (later replaced by the present notation using letters).

Dalton’s law    →   Daltonov zakon

Dalton’s law of partial pressure says that the total pressure eof gaseous mixture is equal to the sum of all gases partial pressures which make that mixture on the condition that they do not interact.

For example, if dry oxygen gas at 900 hPa is saturated with water vapor at 56 hPa, the pressure of the wet gas is 956 hPa.