CHEMISTRY GLOSSARY

Raman effect    →   Ramanov efekt

Raman effect is a type of scattering of electromagnetic radiation in which light suffers a change in frequency and a change in phase as it passes through a material medium. Named according to the Indian physicist C. V. Raman (1889-1970). The intensity of Raman scattering is about one-thousandth of that in Rayleigh scattering in liquids.

rate equation    →   jednadžba brzine reakcije

Rate equation is an equation that describes the dependence of reaction rate on concentrations of reacting species. It always has the form

where a and b are usually integral exponents.

mass-energy equivalence    →   ekvivalencija mase i energije

In the special theory of relativity Einstein demonstrated that neither mass nor energy were conserved separately, but that they could be traded one for the other and only the total "mass-energy" was conserved. The relationship between the mass and the energy is contained in what is probably the most famous equation in science,

Where m is the mass of the object and c is the velocity of light. Cockcroft and Walton (1932) are routinely credited with the first experimental verification of mass-energy equivalence.

strong electrolyte    →   jaki elektrolit

Strong electrolytes are those electrolytes which in water solutions completely dissociate into their ions. They conduct electric current very well.

systematic error    →   sustavna pogreška

Systematic errors have an identifiable cause and affect the accuracy of results.

Nernst’s electrode potential equation    →   Nernstova jednadžba za elektrodni potencijal

For general reaction of some redox system

dependence of electrode potential of redox system upon activity of oxidised and reduced form in solution is described in Nernst’s equation for electrode potential:

where E = to electrode potential of redox system

E° = standard electrode potential of redox system

R = universal gas constant

T = thermodymical temperature

F = Faraday’s constant

z = number of electrons exchanged in redox reaction

a_O = activity of oxidised form

a_R = activity of reduced form

n = stechiometrical coefficient of oxidised form

m = stechiometrical coefficient of reduced form

thermionic emission    →   termionska emisija

Thermionic emission is the boiling off of electrons from heated metals. It gives a source of electrons for cathode ray tubes.

thermodynamic equilibrium    →   termodinmička ravnoteža

Thermodynamic equilibrium is a system equilibrium in which energy that it gains from its surroundings is exactly balanced by the energy that it loses, no matter how much time is allowed to pass.

transuranium element    →   trasuranski element

Transuranium elements are elements with an atomic number higher than 92 (uranium’s atomic number). Transuranium elements are unstable and occur in extremely low concentrations in nature. Most are made artificially.

Tyndall’s effect    →   Tyndallov efekt

Tyndall’s effect occurs when light disperses on colloid particles. This phenomenon can be seen when a ray of light enters in dark room through a small hole. In the beam some dust particles of colloid dimensions can be seen sparkling.