CHEMISTRY GLOSSARY

lanthanides contraction    →   kontrakcija lantanoida

Lanthanides contraction is a reduction of metal and ion diameters from lanthanum to lutetium and it is caused by a core charge growth inside the same shell. Elements which in the periodic system of elements come after lanthanides have, because of lanthanides contraction, smaller diameter than they should have according to their position in the periodic system of elements.

electron configuration    →   elektronska konfiguracija

The electron configuration shows how many electrons there are in an atom or ion and their distribution along orbitals (see Table of electronic configuration of elements). Structure and all regularity in the periodic system depend upon electronic configuration of atoms of elements. Characteristics of elements mainly depend on electronic configuration of the outer shell. Refilling of the new electronic shell atoms of elements of similar electronic configuration emerge as well as in the previous shell, which adds up to periodicities of characteristics of elements.

halogens    →   halogeni elementi

Halogens are the elements fluorine (F) chlorine (Cl), bromine (Br), iodine (I), and astatine (At). They are non-metals, and make up part of the 17 group in the periodic table. Compounds of these elements are called halogenides or halides.

The halogens all have a strong unpleasant odour and will burn flesh. They do not dissolve well in water. The five elements are strongly electronegative. They are oxidising agents, with fluorine being the strongest and astatine being the weakest. They react with most metals and many non-metals.

Halogens form molecules which consist of atoms covalently bonded. With increasing atomic weight there is a gradation in physical properties. For example: Fluorine is a pale green gas of low density. Chlorine is a greenish-yellow gas 1.892 times as dense as fluorine. Bromine is a deep reddish-brown liquid which is three times as dense as water. Iodine is a grayish-black crystalline solid with a metallic appearance. And astatine is a solid with properties which indicate that it is somewhat metallic in character.

lanthanides    →   lantanoidi

Lanthanides (lanthanons, lanthanoids or rare-earth elements) are a series of fourteen elements in the periodic table, generally considered to range in proton number from cerium to lutetium inclusive. It was convenient to divide these elements into the cerium group or light earth: cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu); and the yttrium group or heavy earths: gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb) i lutetium (Lu). The position of lanthanum is somewhat equivocal and, although not itself a lanthanide, it is often included with them for comparative purpose. The lanthanides are sometimes simply called the rare earths. Apart from unstable Pm, the lanthanides are actually not rare. Cerium is the 26. most abundant of all elements, 5 times as abundant as Pb. All are silvery very reactive metals.

mendelevium    →   mendelevij

Mendelevium was discovered by Albert Ghiorso, Bernard G. Harvey, Gregory R. Choppin, Stanley G. Thompson and Glenn T. Seaborg (USA) in 1955. Named in honour of Dimitri Mendeljejev, the Russian chemist who devised the periodic table. It is synthetic radioactive metal. Mendelevium was made by bombarding einsteinium with helium ions.

niobium    →   niobij

Niobium was discovered by Charles Hatchett (England) in 1801. The origin of the name comes from the Greek word Niobe meaning daughter of Tantalus in Greek mythology (tantalum is closely related to niobium in the periodic table). It is shiny white, soft, ductile metal. Exposed surfaces form oxide film. Niobium occurs in a mineral columbite. It is used in stainless steel alloys for nuclear reactors, jets and missiles. Used as an alloy with iron and nickel. It can be used in nuclear reactors and is known to be superconductive when alloyed with tin, aluminium or zirconium.

noble gas    →   plemeniti plin

Noble gas refers to any element of the group of six elements in group 18 of the periodic table. They are helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), and radon (Rn). Unlike most elements, the noble gases are monoatomic. The atoms have stable configurations of electrons. Therefore, under normal conditions they do not form compounds with other elements.

They were generally called inert gases until about 1962 when xenon tetrafluoride, XeF₄, was produced in the laboratory. This was the first report of a stable compound of a noble gas with another single element.

octet rule    →   pravilo okteta

Octet rule states that the chemical properties of the elements repeat on a regular basis with increasing atomic mass, and that the chemical properties of each eight element are similar. Since the inert gases, with the exception of helium have eight electrons in their outer shells, this stable electronic configuration is called the octet rule. In chemical reactions atoms of elements tend to react in such a way as to achieve the electronic configuration of the inert gas nearest to them in the periodic table. There are a number of exceptions to the octet rule.

period    →   perioda

Periods are horizontal rows in the periodic table, each period begin with an alkali metal (one electron in the outermost principal quantum level) and ending with a noble gas (each having eight electrons in the outermost principal quantum level, except for helium, which is limited to two).

quasicrystal    →   kvazikristal

Quasicrystal is a solid having conventional crystalline properties but whose lattice does not display translational periodicity.