CHEMISTRY GLOSSARY

heat of fusion    →   toplina taljenja

Heat of fusion or enthalpy of fusion is the heat required to convert a substance from the solid to the liquid state with no temperature change (also called latent heat of fusion or melting).

heat of hydration    →   toplina hidratacije

Heat of hydration or enthalpy of hydration of ions corresponds to the heat that is released by hydration of one mole of ions at a constant pressure. The more the ion is hydrated, the more heat is released. Degree of hydration depends on the size and charge of ion. The smaller the ion and the greater its charge, it will be the more hydrated.

heat of reaction    →   toplina kemijske reakcije

Heat of reaction or enthalpy of reaction is the heat evolved or absorbed as a result of the complete chemical reaction of molar amounts of the reactants.

electrolytes    →   elektroliti

Electrolytes are substances which, when melted or dissolved in water, conduct electric current. By melting or dissolving they are dissociated into electrically charged particles (ions) which are able to conduct electric current. By passing of electric current the transfer of matter occurs. Positively charged particles (cations) travel towards the negative pole (the cathode) and negatively charged particles (the anions) travel towards the positive pole (the anode). Liquid metals, in which the conduction is by free electrons, are not usually regarded as electrolytes. Solid conductors of ions, as in the sodium-sulphur cell, are also known as electrolytes. Depending upon how it conducts electric current, matter can be divided into strong electrolytes, weak electrolytes and nonconductors.

electron    →   elektron

The electron is an elementary particle with a negative electric charge of (1.602 189 2±0.000 004 6)×10^-19 C and a mass of 1/1837 that of a proton, equivalent to (9.109 534±0.000 047)×10^-31 kg.

In 1897 the British physicist Joseph John (J.J.) Thomson (1856-1940) discovered the electron in a series of experiments designed to study the nature of electric discharge in a high-vacuum cathode-ray tube. Thomson interpreted the deflection of the rays by electrically charged plates and magnets as evidence of bodies much smaller than atoms that he calculated as having a very large value for the charge to mass ratio. Later he estimated the value of the charge itself.

Electrons are arranged in from one to seven shells around the nucleus; the maximum number of electrons in each shell is strictly limited by the laws of physics (2n²). The outer shells are not always filled: sodium has two electrons in the first shell (2×1² = 2), eight in the second (2×2² = 8), and only one in the third (2×3² = 18). A single electron in the outer shell may be attracted into an incomplete shell of another element, leaving the original atom with a net positive charge. Valence electrons are those that can be captured by or shared with another atom.

Electrons can be removed from the atoms by heat, light, electric energy, or bombardment with high-energy particles. Decaying radioactive nuclei spontaneously emit free electrons, called β particles.

heat of sublimation    →   toplina sublimacije

Heat of sublimation or enthalpy of sublimation is the energy required to convert one mole of a substance from the solid to the gas state (sublimation) without the appearance of the liquid state.

heat transfer    →   prijenos topline

From observations and experiments it has been found that heat energy can be transferred from one position to another through three different modes: conduction, convection and radiation.

hecto    →   hekto

Hecto, symbol h, is a prefix used in the metric system to denote 100 times. For example, 100 c = 1 hC.

Heisenberg uncertainty principle    →   Heisenbergov princip neodređenosti

Heisenberg uncertainty principle is the principle that it is not possible to know with unlimited accuracy both the position and momentum of a particle. The German physicist Werner Heisenberg (1901-1976) discovered this principle in 1927.

henry    →   henri

Henry (H) is the SI derived unit of inductance equal to the inductance of a closed circuit in which an e.m.f. of one volt is produced when the electric current in the circuit varies uniformly at a rate of one ampere per second (H = V·s/A). The unit was named after the American physicst Joseph Henry (1797-1878).