CHEMISTRY GLOSSARY

Avogadro’s law    →   Avogadrov zakon

Avogadro’s law: Equal volumes of all gases contain equal numbers of molecules at the same pressure and temperature. The law, often called Avogadro’s hypothesis, is true only for ideal gases. It was proposed in 1811 by Italian chemist Amadeo Avogadro (1776-1856).

azeotrope    →   azeotropi

Azeotrope is a mixture of two liquids that boils at constant composition, i.e. the composition of the vapour is the same as that of the liquid. Azeotropes occur because of deviations in Raoult’s law leading to a maximum or minimum in the boiling point - composition diagram. The composition of an azeotrope depends on the pressure.

bar    →   bar

Bar (bar) is a unit of pressure equal to 10⁵ Pa. Its use is temporarily maintained with the SI. The milibar (100 Pa) is commonly used in meteorology.

Arrhenius equation    →   Arheniusova jednadžba

In 1889, Svante Arrhenius explained the variation of rate constants with temperature for several elementary reactions using the relationship

where the rate constant k is the total frequency of collisions between reaction molecules A times the fraction of collisions exp(-E_a/RT) that have an energy that exceeds a threshold activation energy E_a at a temperature of T (in kelvin). R is the universal gas constant.

arsenic    →   arsen

Arsenic was discovered by Albertus Magnus (Germany) in 1250. The origin of the name comes from the Greek word arsenikon meaning yellow orpiment. It is steel-grey, brittle semi-metal. Resists water, acids and alkalis. Tarnishes in air, burns in oxygen. Highly toxic by inhalation or ingestion. Arsenic is found in mispickel (arsenopyrite). Many of its compounds are deadly poison and used as weed killer and rat poison. Used in semiconductors. Some compounds, called arsenides, are used in the manufacture of paints, wallpapers and ceramics.

asbestos    →   azbest

Asbestos is any one of a group of fibrous amphibole minerals (from the silicate group). It has widespread commercial uses because of its resistance to heat, chemical inertness., and high electrical resistance. Since 1970s short asbestos fibres have been recognized as a cause of asbestosis, a serious lung disorder, and mesothelioma, a fatal form of lung cancer. These concerns have limited its use and imposed many safety procedures when it is used.

asparagine    →   asparagin

Asparagine is neutral amino acids with polar side chains. The polar amino acids are an important class of amino acids since they provide many of the functional groups found in proteins. Asparagine is a common site for attachment of carbohydrates in glycoproteins. In general this is not very reactive residues. Asparagine is amide derivative of aspartic acid. Asparagine is not essential for humans, which means that it can be synthesized from central metabolic pathway intermediates and is not required in the diet.

• Abbreviations: Asn, N
• IUPAC name: 2,4-diamino-4-oxobutanoic acid
• Molecular formula: C₄H₈N₂O₃
• Molecular weight: 132.12 g/mol

barrier film    →   barijerni film

Barrier film is a thin, continuous, non-porous, electrically insulating film on metal surfaces (usually comprised of oxides).

barytes    →   barit

Barytes is an orthorhombic mineral, form barium sulphate, BaSO₄, the chief of barium. It is usually white but my also be yellow, grey or brown. Large deposits occur in Andalusia, Spain and in the USA.

basic Bessemer process    →   bazni Bessemerov proces

Basic Bessemer process is the process of steelmaking in a way that steel, melted iron and limestone are put in the blast-furnace after which the metal oxygen is released in gushes in order to oxidise the impurities.