CHEMISTRY GLOSSARY

molecule    →   molekula

Molecule is the smallest part of a chemical compound that can take part in a chemical reaction. The atoms of a molecule are held together by chemical bonds.

monobasic acid    →   monobazična kiselina

Monobasic acids are acids that have only one replacable hydrogen atom per molecule (HCl, HNO₃).

monodentate ligand    →   monodentantni ligand

Monodentate ligand is a ligand that has only one atom that coordinates directly to the central atom in a complex. For example, ammonia and chloride ion are monodentate ligands of copper in the complexes [Cu(NH₃)₆]²⁺ and [CuCl₆]²⁺.

nuclide    →   nuklid

Nuclide is a species of atoms in which each atom has identical atomic number Z and identical mass number A. For example, a carbon-14 (C-14 or ¹⁴C) nuclide is the nucleus of a carbon atom, which has six protons and eight neutrons.

electron    →   elektron

The electron is an elementary particle with a negative electric charge of (1.602 189 2±0.000 004 6)×10^-19 C and a mass of 1/1837 that of a proton, equivalent to (9.109 534±0.000 047)×10^-31 kg.

In 1897 the British physicist Joseph John (J.J.) Thomson (1856-1940) discovered the electron in a series of experiments designed to study the nature of electric discharge in a high-vacuum cathode-ray tube. Thomson interpreted the deflection of the rays by electrically charged plates and magnets as evidence of bodies much smaller than atoms that he calculated as having a very large value for the charge to mass ratio. Later he estimated the value of the charge itself.

Electrons are arranged in from one to seven shells around the nucleus; the maximum number of electrons in each shell is strictly limited by the laws of physics (2n²). The outer shells are not always filled: sodium has two electrons in the first shell (2×1² = 2), eight in the second (2×2² = 8), and only one in the third (2×3² = 18). A single electron in the outer shell may be attracted into an incomplete shell of another element, leaving the original atom with a net positive charge. Valence electrons are those that can be captured by or shared with another atom.

Electrons can be removed from the atoms by heat, light, electric energy, or bombardment with high-energy particles. Decaying radioactive nuclei spontaneously emit free electrons, called β particles.

electronegativity    →   elektronegativnost

Electronegativity is a parameter originally introduced by L. Pauling which describes, on a relative basis, the power of an atom to attract electrons. For example, in hydrogen chloride, the chlorine atom is more electronegative than the hydrogen and the molecule is polar, with a negative charge on the chlorine atom.

There are various ways of assigning values for the electronegativity of an element. Pauling electronegativities are based on bond dissociation energies using a scale in which fluorine, the most electronegative element, has the value 4 and francium, the lowest electronegative element, has the value 0.7.

octet    →   oktet

Octet is scientific law stating that all atoms, except those of hydrogen and helium, require eight electrons in the outermost energy level to maintain chemical stability.

organic chemistry    →   organska kemija

Organic chemistry is a science about all compounds which consist of carbon atoms, except carbonates and oxides of carbon.

organometallic compound    →   organometalni spoj

Organometallic compounds are compounds in which there is a covalent connection between atoms of carbons and atoms of metal (C-Me).

Pauli exclusion principle    →   Paulijev princip zabrane

Pauli exclusion principle is the statement that two electrons in an atom cannot have identical all four quantum numbers. It was first formulated in 1925 by the Austrian-born Swiss physicst Wolfgang Ernst Pauli (1900-1958).